In situ observation of a reversible single crystal-to-single-crystal apical-ligand exchange reaction in a hydrogen-bonded 2D coordination network

被引：152
|
作者：
Takaoka, K
Kawano, M
Tominaga, M
Fujita, M
机构：
[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan
[2] Genesis Res Inst Inc, Bunkyo Ku, Tokyo 1138656, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 14期
关键词：
cobalt; coordination polymers; host-guest systems; hydrogen bonds; ligand design;
D O I：
10.1002/anie.200462214
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Aqua and nitrate forms of a CoII center are reversibly interconverted within a square-grid complex because of flexible side chains attached to a rodlike ligand (see scheme; Co yellow, N blue, O red). The ligand exchange proceeds in a single-crystal-to-single-crystal fashion despite the drastic structural changes at the metal center. All processes are observed by in situ X-ray crystallography. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2151 / 2154
页数：4
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