Vicarious nucleophilic substitution of hydrogen proceeding via heterocyclic ring opening

被引：10

作者：

Makosza, M

Sypniewski, M

Glinka, T

机构：

[1] Institute of Organic Chemistry, Polish Academy of Sciences, 01-224 Warsaw

来源：

TETRAHEDRON | 1996年 / 52卷 / 09期

关键词：

D O I：

10.1016/0040-4020(95)01104-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Carbanions of five-membered S-heterocycles react with nitroarenes via the ring-opening VNS reaction or oxidative nucleophilic substitution of hydrogen. The reaction course is affected by rigidity of the ring.

引用

页码：3189 / 3194

页数：6

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