Silicon layer intercalation of centimeter-scale, epitaxially grown monolayer graphene on Ru(0001)

被引:102
作者
Mao, Jinhai [1 ]
Huang, Li [1 ]
Pan, Yi [1 ]
Gao, Min [1 ]
He, Junfeng [1 ]
Zhou, Haitao [1 ]
Guo, Haiming [1 ]
Tian, Yuan [1 ]
Zou, Qiang [1 ]
Zhang, Lizhi [1 ]
Zhang, Haigang [1 ]
Wang, Yeliang [1 ]
Du, Shixuan [1 ]
Zhou, Xingjiang [1 ]
Castro Neto, A. H. [2 ]
Gao, Hong-Jun [1 ]
机构
[1] Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China
[2] Natl Univ Singapore, Dept Phys, Graphene Res Ctr, Singapore 117542, Singapore
基金
美国国家科学基金会;
关键词
conduction bands; elemental semiconductors; graphene; intercalation compounds; monolayers; photoelectron spectra; scanning tunnelling microscopy; scanning tunnelling spectroscopy; semiconductor epitaxial layers; semiconductor-insulator boundaries; silicon; valence bands; ELECTRONIC-STRUCTURE; SPECTROSCOPY; SURFACE;
D O I
10.1063/1.3687190
中图分类号
O59 [应用物理学];
学科分类号
摘要
We develop a strategy for graphene growth on Ru(0001) followed by silicon-layer intercalation that not only weakens the interaction of graphene with the metal substrate but also retains its superlative properties. This G/Si/Ru architecture, produced by silicon-layer intercalation approach (SIA), was characterized by scanning tunneling microscopy/spectroscopy and angle resolved electron photoemission spectroscopy. These experiments show high structural and electronic qualities of this new composite. The SIA allows for an atomic control of the distance between the graphene and the metal substrate that can be used as a top gate. Our results show potential for the next generation of graphene-based materials with tailored properties. (C) 2012 American Institute of Physics. [doi: 10.1063/1.3687190]
引用
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页数:4
相关论文
共 22 条
[1]   Quasiparticle dynamics in graphene [J].
Bostwick, Aaron ;
Ohta, Taisuke ;
Seyller, Thomas ;
Horn, Karsten ;
Rotenberg, Eli .
NATURE PHYSICS, 2007, 3 (01) :36-40
[2]   The electronic properties of graphene [J].
Castro Neto, A. H. ;
Guinea, F. ;
Peres, N. M. R. ;
Novoselov, K. S. ;
Geim, A. K. .
REVIEWS OF MODERN PHYSICS, 2009, 81 (01) :109-162
[3]   The carbon new age [J].
Castro Neto, Antonio H. .
MATERIALS TODAY, 2010, 13 (03) :12-17
[4]   Structural coherency of graphene on Ir(111) [J].
Coraux, Johann ;
N'Diaye, Alpha T. ;
Busse, Carsten ;
Michely, Thomas .
NANO LETTERS, 2008, 8 (02) :565-570
[5]   The role of the interlayer state in the electronic structure of superconducting graphite intercalated compounds [J].
Csányi, G ;
Littlewood, PB ;
Nevidomskyy, AH ;
Pickard, CJ ;
Simons, BD .
NATURE PHYSICS, 2005, 1 (01) :42-45
[6]   The formation of an energy gap in graphene on ruthenium by controlling the interface [J].
Enderlein, C. ;
Kim, Y. S. ;
Bostwick, A. ;
Rotenberg, E. ;
Horn, K. .
NEW JOURNAL OF PHYSICS, 2010, 12
[7]   Graphene: Status and Prospects [J].
Geim, A. K. .
SCIENCE, 2009, 324 (5934) :1530-1534
[8]   Electronic decoupling of an epitaxial graphene monolayer by gold intercalation [J].
Gierz, Isabella ;
Suzuki, Takayuki ;
Weitz, R. Thomas ;
Lee, Dong Su ;
Krauss, Benjamin ;
Riedl, Christian ;
Starke, Ulrich ;
Hoechst, Hartmut ;
Smet, Jurgen H. ;
Ast, Christian R. ;
Kern, Klaus .
PHYSICAL REVIEW B, 2010, 81 (23)
[9]   SUPERCONDUCTIVITY IN GRAPHITIC COMPOUNDS [J].
HANNAY, NB ;
GEBALLE, TH ;
MATTHIAS, BT ;
ANDRES, K ;
SCHMIDT, P ;
MACNAIR, D .
PHYSICAL REVIEW LETTERS, 1965, 14 (07) :225-&
[10]   Intercalation of metal islands and films at the interface of epitaxially grown graphene and Ru(0001) surfaces [J].
Huang, Li ;
Pan, Yi ;
Pan, Lida ;
Gao, Min ;
Xu, Wenyan ;
Que, Yande ;
Zhou, Haitao ;
Wang, Yeliang ;
Du, Shixuan ;
Gao, H. -J. .
APPLIED PHYSICS LETTERS, 2011, 99 (16)