trans-dichloro-cis-bis(3,6-dimethylcarbazolyl)-cis-bis(tetrahydrofuran)zirconium(IV) benzene sesquisolvate

被引：4
作者：
Nygren, CL
Bragg, MET
Turner, JFC
机构：
[1] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
[2] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2004年 / 60卷
关键词：
D O I：
10.1107/S0108270103026258
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the title compound, [ZrCl2(C14H12N)(2)(C4H8O)(2)].1.5C(6)H(6), the Zr atom is pseudo-octahedral, with two Cl atoms in trans positions and two tetrahydrofuran molecules in cis positions. The two 3,6-dimethylcarbazolyl ligands are in cis positions and are canted with respect to one another. The two Zr-N distances are 2.1148 (18) and 2.1236 (18) Angstrom, and the N-Zr-N angle is 95.08 (7)degrees. The title compound crystallizes as the benzene solvate, with one of the benzene molecules positioned on an inversion center.
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页码：M4 / M6
页数：3
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