The Dielectric Behavior of BaTiO3 Based Ceramics Doped With La/Mn

被引:7
作者
Ding Shihua [1 ]
Zhao Ping [1 ]
Song Tianxiu [1 ]
Yang Xiaojing [2 ]
机构
[1] Xihua Univ, Sch Mat Sci & Engn, Chengdu 610039, Peoples R China
[2] Xihua Univ, Sch Energy & Environm, Chengdu 610039, Peoples R China
基金
中国国家自然科学基金;
关键词
Dielectric relaxation; diffuse phase transitions; remanent polarization; coercive electric field;
D O I
10.1080/00150193.2012.671107
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
BaTiO3 based ferroelectric ceramics (with some additives such as SnO2 and ZrO2 etc) were prepared by solid state reaction. Mn2+ or Mn3+ as an acceptor substituting for Ti4+ in B sites and La3+ as a donor substituting for Ba2+ in A sites were co-doped in BaTiO3 based ceramics. The effect of the donor and acceptor (La/Mn) on the dielectric dispersion properties of BaTiO3 based ceramics was investigated. The Mn = 1.6% mol and La = 0, 0.10%, 1.1%, 1.4% mole. When the content of La (donor) increased, the ferroelectric relaxor behavior was observed and the dielectric permittivity decreased. When La varied from 0% to 1.4% mol (Mn = 1.6% mol), remnant polarization from 7.96 to 0.58 mu C/cm(2), coercive field from 4.4 to 1.0 kV/cm, and piezoelectric constant d(33) from 90 to 35 pC/N respectively.
引用
收藏
页码:66 / 71
页数:6
相关论文
共 13 条
  • [1] FORCE-CONSTANT AND EFFECTIVE MASS OF 90-DEGREES DOMAIN-WALLS IN FERROELECTRIC CERAMICS
    ARLT, G
    PERTSEV, NA
    [J]. JOURNAL OF APPLIED PHYSICS, 1991, 70 (04) : 2283 - 2289
  • [2] EFFECTS OF GRAIN GROWTH ON DISTRUBUTION OF NB IN BATIO3 CERAMICS
    BUESSEM, WR
    KAHN, M
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1971, 54 (09) : 458 - &
  • [3] FERROELECTRICS WITH A GLASSY POLARIZATION PHASE
    BURNS, G
    DACOL, FH
    [J]. FERROELECTRICS, 1990, 104 : 25 - 35
  • [4] HENNINGS D, 1984, J AM CERAM SOC, V67, P249, DOI 10.1111/j.1151-2916.1984.tb18841.x
  • [5] Role of yttrium and magnesium in the formation of core-shell structure of BaTiO3 grains in MLCC
    Kim, Chang-Hoon
    Park, Kum-Jin
    Yoon, Yeo-Joo
    Hong, Min-Hee
    Hong, Jeong-Oh
    Hur, Kang-Heon
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2008, 28 (06) : 1213 - 1219
  • [6] Nonstoichiometry and defect structure of Mn-doped BaTiO3-δ
    Lee, DK
    Yoo, HI
    Becker, KD
    [J]. SOLID STATE IONICS, 2002, 154 : 189 - 193
  • [7] Electrical and structural characteristics of lanthanum-doped barium titanate ceramics
    Morrison, FD
    Sinclair, DC
    West, AR
    [J]. JOURNAL OF APPLIED PHYSICS, 1999, 86 (11) : 6355 - 6366
  • [8] Doping mechanisms and electrical properties of La-doped BaTiO3 ceramics
    Morrison, FD
    Sinclair, DC
    West, AR
    [J]. INTERNATIONAL JOURNAL OF INORGANIC MATERIALS, 2001, 3 (08): : 1205 - 1210
  • [9] Okazaki K., 1965, J JAPANESE CERAMIC S, V73, P60
  • [10] THE ROLE OF B-SITE CATION DISORDER IN DIFFUSE PHASE-TRANSITION BEHAVIOR OF PEROVSKITE FERROELECTRICS
    SETTER, N
    CROSS, LE
    [J]. JOURNAL OF APPLIED PHYSICS, 1980, 51 (08) : 4356 - 4360