Recent Advances in Noble-Metal-Free Catalysts for Electrocatalytic Synthesis of Ammonia under Ambient Conditions

被引：13
|
作者：
Xiang, Zhongyuan [1 ,2 ,3 ,4 ,5 ]
Li, Lihong [1 ,2 ,3 ,4 ]
Wang, Ying [1 ,2 ,3 ,4 ]
Song, Yanlin [1 ,2 ,3 ,4 ]
机构：
[1] Chinese Acad Sci, Key Lab Green Printing, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
[3] Beijing Engn Res Ctr Nanomat Green Printing Techn, Beijing 100190, Peoples R China
[4] Beijing Natl Lab Mol Sci BNLMS, Beijing 100190, Peoples R China
[5] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2020年 / 15卷 / 12期
基金：
国家重点研发计划; 中国国家自然科学基金;
关键词：
nitrogen fixation; NH3; electrosynthesis; nitrogen reduction reaction; noble-metal-free; ELECTROCHEMICAL N-2 REDUCTION; SINGLE-ATOM CATALYSTS; NITROGEN REDUCTION; HIGHLY EFFICIENT; DOPED GRAPHENE; IRON CATALYST; DINITROGEN REDUCTION; BISMUTH NANOSHEETS; ORGANIC FRAMEWORKS; RATIONAL DESIGN;
D O I：
10.1002/asia.202000310
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ammonia is an essential chemical for producing fertilizers and energy carriers. However, the industrial Haber-Bosch process causes huge CO2 emissions and energy waste. As a promising alternative for Haber-Bosch process, electrochemical synthesis of ammonia has drawn much attention. Catalysts, as a vital part of electrochemical nitrogen reduction reaction (NRR), have developed rapidly in recent years. Compared to noble-metal catalysts, noble-metal-free catalysts possess a low-cost advantage. In this review, noble-metal-free catalysts, including metal-based materials, metal organic frameworks (MOFs), MXenes, and metal-free materials, are summarized. In addition, effective design strategies are discussed, along with the main problems and some potential directions of noble-metal-free NRR catalysts.
引用
收藏
页码：1791 / 1807
页数：17
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