Towards copper-free nanocapsules obtained by orthogonal interfacial "click" polymerization in miniemulsion

被引:38
作者
Siebert, Joerg Max [1 ]
Baier, Grit [1 ]
Musyanovych, Anna [1 ]
Landfester, Katharina [1 ]
机构
[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
关键词
TERMINAL ALKYNES; CHEMISTRY; AZIDE; POLYCONDENSATION; CYCLOADDITIONS; SURFACES;
D O I
10.1039/c2cc30253e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A facile method to produce nanocapsules by copper-free interfacial "click"-polymerization as orthogonal reaction for the encapsulation of functional molecules is successfully performed using stable miniemulsion droplets. Difunctional azides and alkynes have been used for polymerization around the miniemulsion droplets, leading to the formation of nanocapsules. The results were compared with copper-catalyzed systems.
引用
收藏
页码:5470 / 5472
页数:3
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