Methodology Development and Physical Organic Chemistry: A Powerful Combination for the Advancement of Glycochemistry

被引：108

作者：

Crich, David ^{[1
]}

机构：

[1] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 22期

关键词：

FREE-RADICAL REACTIONS; ONE-POT SYNTHESIS; BETA-D-MANNOPYRANOSIDES; SOLID-PHASE SYNTHESIS; ALPHA-SELECTIVE SIALYLATIONS; HYDROGEN-ATOM ABSTRACTION; ACETYL-NEURAMINIC ACID; STEREOSELECTIVE-SYNTHESIS; STEREOCONTROLLED SYNTHESIS; PROTECTING GROUP;

D O I：

10.1021/jo2017026

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This Perspective outlines work in the Crich group on the diastereoselective synthesis of the so-called difficult classes of glycosidic bond: the 2-deoxy-beta-glycopyranosides, the beta-mannopyranosides, the alpha-sialosides, the alpha-glucopyranosides, and the beta-arabinofuranosides with an emphasis on the critical interplay between mechanism and methodology development.

引用

收藏

页码：9193 / 9209

页数：17

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