Hydrogen Production from Methane Decomposition Using Nano Metal Oxides

被引:6
作者
Jyoti [1 ]
Ashok, C. H. [2 ]
Srilatha, K. [3 ]
Patil, Nirdosh [1 ]
Chakra, C. H. Shilpa [2 ]
机构
[1] Appa Inst Engn & Technol, Gulbarga 585101, Karnataka, India
[2] JNTUH, Inst Sci & Technol, Ctr Nano Sci & Technol, Hyderabad 85, Telangana, India
[3] JNTUH, Inst Sci & Technol, Ctr Alternat Energy Opt, Hyderabad 85, Telangana, India
关键词
Thermal decomposition; metallic catalyst; solution combustion; XRD; BET; PSA; CATALYTIC DECOMPOSITION; PARTIAL OXIDATION; BIOMASS; PYROLYSIS; HYDROCARBONS; GASIFICATION; TEMPERATURE; FRUCTOSE; GLUCOSE; REACTOR;
D O I
10.1016/j.matpr.2017.09.082
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nanotechnology is like an umbrella, under this maximum all the fields, branches are developing, like a green-house effect for plant. Nanotechnology can provide new concepts for the energy department which can utilise and provide new sources for all energy challenges, like generation, renewable and storage with less energy consumption, that provide an economy to the development to country. This can be achieved with the help of hydrogen for energy application; thermo catalytic decomposition of methane is a simple process to produces carbon free hydrogen. Mono metallic NiO, Co3O4, ZrO2 and ZnO catalyst were synthesised by a solution combustion process. The methane decomposition and catalyst activity test is done at fixed bed reactor with a methane flow rate of 54 SCCM with an operation condition of 850 degrees C temperature under atmospheric pressure respectively. The catalyst is characterised by BET, XRD and PSA. The complete observation and catalyst performance shows that catalyst activity is high at the initial time of reaction and decreases with deposition (time) of carbon over the catalyst. As resultant the methane decomposition showed activity nearly 3h for all the catalyst. Comparison study shows that hydrogen yield and deposited carbon occurs (catalyst activity) is completely based on particle size, Surface area and Pore volume of material used. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:11679 / 11689
页数:11
相关论文
共 37 条
[1]   Hydrogen production from thermo-catalytic decomposition of methane using carbon black catalysts in an indirectly-irradiated tubular packed-bed solar reactor [J].
Abanades, Stephane ;
Kimura, Hiroyuki ;
Otsuka, Hiroyuki .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (33) :18770-18783
[2]  
[Anonymous], 2009, WORLD FUTURE
[3]  
[Anonymous], 2003, BAS EN SCI WORK SHOP
[4]   Energy efficient production of hydrogen and syngas from biomass: Development of low-temperature catalytic process for cellulose gasification [J].
Asadullah, M ;
Ito, SI ;
Kunimori, K ;
Yamada, M ;
Tomishige, K .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2002, 36 (20) :4476-4481
[5]  
Ashok Chinthkuntla, CDS NANOPARTICLES TH
[6]  
chukwu Cletus, 2008, THESIS
[7]   Aqueous-phase reforming of ethylene glycol on silica-supported metal catalysts [J].
Davda, RR ;
Shabaker, JW ;
Huber, GW ;
Cortright, RD ;
Dumesic, JA .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2003, 43 (01) :13-26
[8]   Recovery of chemicals and gasoline-range fuels from plastic wastes via pyrolysis [J].
Demirbas, A .
ENERGY SOURCES, 2005, 27 (14) :1313-1319
[9]   Hydrogen from biomass via pyrolysis: Relationships between yield of hydrogen and temperature [J].
Demirbas, A ;
Arin, G .
ENERGY SOURCES, 2004, 26 (11) :1061-1069
[10]  
Demirbas MF, 2006, ENERG SOURCE PART A, V28, P245, DOI 10.1080/009083190890003