Reversible and irreversible emergence of chiroptical signals in J-aggregates of achiral 4-sulfonatophenyl substituted porphyrins: intrinsic chirality vs. chiral ordering in the solution

被引：13
作者：
Arteaga, Oriol [1 ,2 ]
El-Hachemi, Zoubir [3 ,4 ]
Canillas, Adolf [1 ,2 ]
Crusats, Joaquim [3 ,4 ]
Rovira, Meritxell [3 ]
Ribo, Josep M. [3 ,4 ]
机构：
[1] Univ Barcelona, Dept Appl Phys, E-08028 Barcelona, Catalonia, Spain
[2] Inst Nanosci & Nanotechnol IN2UB, FEMAN Grp, E-08028 Barcelona, Catalonia, Spain
[3] Univ Barcelona, Dept Quim Inorgan & Organ, Secccio Organ, E-08028 Barcelona, Catalonia, Spain
[4] Inst Cosmos Sci IEEC UB, E-08028 Barcelona, Catalonia, Spain
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 72期
关键词：
SUPRAMOLECULAR CHIRALITY; CIRCULAR-DICHROISM; SPECTROSCOPIC VISUALIZATION; SYMMETRY-BREAKING; KINETIC CONTROL; SELECTION; FLOWS; INDUCTION; HANDEDNESS; VORTICES;
D O I：
10.1039/c6cc05709h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Mueller matrix polarimetry distinguishes the different origins of the reversible and irreversible chiroptical effects emerging in stirred solutions of J-aggregate nanoparticles: the reversible effect is due to an anisotropic ordering in the solution and the irreversible one is due to a bias from the racemic composition of intrinsically chiral structures.
引用
收藏
页码：10874 / 10877
页数：4
相关论文
共 45 条
[1]   Structure vs. excitonic transitions in self-assembled porphyrin nanotubes and their effect on light absorption and scattering [J].
Arteaga, Oriol ;
Canillas, Adolf ;
El-Hachemi, Zoubir ;
Crusats, Joaquim ;
Ribo, Josep M. .
NANOSCALE, 2015, 7 (48) :20435-20441
[2]   Mueller matrix microscope with a dual continuous rotating compensator setup and digital demodulation [J].
Arteaga, Oriol ;
Baldris, Marta ;
Anto, Joan ;
Canillas, Adolf ;
Pascual, Esther ;
Bertran, Enric .
APPLIED OPTICS, 2014, 53 (10) :2236-2245
[3]   Mueller matrix polarimetry with four photoelastic modulators: theory and calibration [J].
Arteaga, Oriol ;
Freudenthal, John ;
Wang, Baoliang ;
Kahr, Bart .
APPLIED OPTICS, 2012, 51 (28) :6805-6817
[4]   Emergence of Supramolecular Chirality by Flows [J].
Arteaga, Oriol ;
Canillas, Adolf ;
Crusats, Joaquim ;
El-Hachemi, Zoubir ;
Llorens, Joan ;
Sacristan, Eduardo ;
Ribo, Josep M. .
CHEMPHYSCHEM, 2010, 11 (16) :3511-3516
[5]   Reversible Mechanical Induction of Optical Activity in Solutions of Soft-Matter Nanophases [J].
Arteaga, Oriol ;
Escudero, Carlos ;
Oncins, Gerard ;
El-Hachemi, Zoubir ;
Llorens, Joan ;
Crusats, Joaquim ;
Canillas, Adolf ;
Ribo, Josep M. .
CHEMISTRY-AN ASIAN JOURNAL, 2009, 4 (11) :1687-1696
[6]   Pseudopolar decomposition of the Jones and Mueller-Jones exponential polarization matrices [J].
Arteaga, Oriol ;
Canillas, Adolf .
JOURNAL OF THE OPTICAL SOCIETY OF AMERICA A-OPTICS IMAGE SCIENCE AND VISION, 2009, 26 (04) :783-793
[7]   Scaling the Chirality in Porphyrin J-Nanoaggregates [J].
Castriciano, Maria Angela ;
Romeo, Andrea ;
De Luca, Giovanna ;
Villari, Valentina ;
Scolaro, Luigi Monsu ;
Micali, Norberto .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (04) :765-767
[8]   Vortexes and Nanoscale Chirality [J].
D'Urso, Alessandro ;
Randazzo, Rosalba ;
Lo Taro, Letizia ;
Purrello, Roberto .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (01) :108-112
[9]   Role of the Hydrophobic Effect in the Transfer of Chirality from Molecules to Complex Systems: From Chiral Surfactants to Porphyrin/Surfactant Aggregates [J].
El-Hachemi, Zoubir ;
Mancini, Giovanna ;
Ribo, Josep M. ;
Sorrenti, Alessandro .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (45) :15176-15184
[10]   On the mechano-chiral effect of vortical flows on the dichroic spectra of 5-phenyl-10,15,20-tris(4-sulfonatophenyl)porphyrin J-aggregates [J].
El-Hachemi, Zoubir ;
Arteaga, Oriol ;
Canillas, Adolf ;
Crusats, Joaquim ;
Escudero, Carlos ;
Kuroda, Reiko ;
Harada, Takunori ;
Rosa, Monica ;
Ribo, Josep M. .
CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (21) :6438-6443
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