Study on new phase transitions in Cs2CaCl4•2H2O single crystals by observation of 133Cs NMR

The (CS)-C-133 1/2 -> - 1/2 spin-lattice relaxation rate, T-1(-1), and the spin-spin relaxation rate, T-2(-1), for a Cs2CaCl4-2H(2)O single crystal have been measured in function of temperature. The dominant relaxation mechanism of this crystal over the whole temperature range investigated here proceeds via quadrupole interaction. The changes in the (CS)-C-133 spin-lattice relaxation rate near 325 K (= T-c1) and 360 K (= T-c2) correspond to phase transitions in the crystal. The change in the spin-lattice relaxation rate at T-c1 is small because the crystal lattice does not change very much during this phase transition. The change in T-1(-1) near T-c2 is due to the critical slowing down of the soft mode that typically occurs in structural phase transitions. The temperature dependence of the spin-lattice relaxation rate for this crystal has maximum values at about 240 K, which is attributable to the effect of molecular motion as described by Bloembergen-Purcell-Pound theory. The phase transition temperatures T-c1 and T-c2 obtained from the temperature dependence of the relaxation rate is also clear from data obtained using differential scanning calorimetry. Therefore, we know that previously unreported phase transitions occur at 325 and 360 K. (c) 2005 Elsevier Ltd. All rights reserved.