Chloride induced reinforcement corrosion: Electrochemical monitoring of initiation stage and chloride threshold values

被引:191
作者
Angst, Ueli M. [1 ]
Elsener, Bernhard [2 ,3 ]
Larsen, Claus K. [1 ,4 ]
Vennesland, Oystein [1 ]
机构
[1] NTNU Norwegian Univ Sci & Technol, Dept Struct Engn, N-7491 Trondheim, Norway
[2] ETH Honggerberg, Inst Bldg Mat IfB, ETH Zurich, CH-8093 Zurich, Switzerland
[3] Univ Cagliari, Dept Inorgan & Analyt Chem, I-09142 Cagliari, Italy
[4] Norwegian Publ Rd Adm, N-0033 Oslo, Norway
关键词
Steel reinforced concrete; Polarisation; Pitting corrosion; Repassivation; CONCRETE RESISTIVITY MEASUREMENTS; SPECIMEN SIZE; FLY-ASH; ELECTRICAL-RESISTIVITY; CONTAMINATED CONCRETE; PORE SOLUTIONS; STEEL; POTENTIALS; INTERFACE; DIFFUSION;
D O I
10.1016/j.corsci.2011.01.025
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Reinforcement steel embedded in six different concrete mixes was exposed to chloride by wetting/drying cycles. Various parameters were continuously monitored during more than 1 year. Cement replacement with fly ash had beneficial long-term effects regarding chloride penetration resistance. Concerning corrosion performance, by far the most dominant influencing parameter was the steel/concrete interface since corrosion initiated on the lower side of the rebar (with respect to casting direction) regardless of binder type and w/b ratio. In many cases, after the first signs of depassivation, a marked increase in chloride content was required to prevent repassivation and to enable stable pit growth. (c) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1451 / 1464
页数:14
相关论文
共 57 条
[1]   Electrochemistry and surface chemistry of stainless steels in alkaline media simulating concrete pore solutions [J].
Addari, D. ;
Elsener, B. ;
Rossi, A. .
ELECTROCHIMICA ACTA, 2008, 53 (27) :8078-8086
[2]   Chloride threshold dependence of pitting potential of reinforcements [J].
Alonso, C ;
Castellote, M ;
Andrade, C .
ELECTROCHIMICA ACTA, 2002, 47 (21) :3469-3481
[3]  
American Society for Testing and Material, C1152 ASTM
[4]   Detecting critical chloride content in concrete using embedded ion selective electrodes - effect of liquid junction and membrane potentials [J].
Angst, U. ;
Vennesland, O. .
MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION, 2009, 60 (08) :638-643
[5]  
ANGST U, 2010, CONSEC 10 6 INT C CO, V1, P359
[6]   Probabilistic considerations on the effect of specimen size on the critical chloride content in reinforced concrete [J].
Angst, Ueli ;
Ronnquist, Anders ;
Elsener, Bernhard ;
Larsen, Claus K. ;
Vennesland, Oystein .
CORROSION SCIENCE, 2011, 53 (01) :177-187
[7]   Diffusion potentials in porous mortar in a moisture state below saturation [J].
Angst, Ueli ;
Elsener, Bernhard ;
Myrdal, Roar ;
Vennesland, Oystein .
ELECTROCHIMICA ACTA, 2010, 55 (28) :8545-8555
[8]   Potentiometric determination of the chloride ion activity in cement based materials [J].
Angst, Ueli ;
Elsener, Bernhard ;
Larsen, Claus K. ;
Vennesland, Oystein .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2010, 40 (03) :561-573
[9]   Critical chloride content in reinforced concrete - A review [J].
Angst, Ueli ;
Elsener, Bernhard ;
Larsen, Claus K. ;
Vennesland, Oystein .
CEMENT AND CONCRETE RESEARCH, 2009, 39 (12) :1122-1138
[10]   Diffusion potentials as source of error in electrochemical measurements in concrete [J].
Angst, Ueli ;
Vennesland, Oystein ;
Myrdal, Roar .
MATERIALS AND STRUCTURES, 2009, 42 (03) :365-375