Plasmonic Dye-Sensitized Solar Cells Using Core-Shell Metal-Insulator Nanoparticles

被引:527
作者
Brown, Michael D. [1 ]
Suteewong, Teeraporn [2 ]
Kumar, R. Sai Santosh [3 ]
D'Innocenzo, Valerio [3 ]
Petrozza, Annamaria [3 ]
Lee, Michael M. [1 ]
Wiesner, Ulrich [2 ]
Snaith, Henry J. [1 ]
机构
[1] Univ Oxford, Dept Phys, Clarendon Lab, Oxford OX1 3PU, England
[2] Cornell Univ, Dept Mat Sci & Engn, Ithaca, NY 14853 USA
[3] IIT PoliMI, Ctr Nano Sci & Technol, I-20133 Milan, Italy
基金
英国工程与自然科学研究理事会; 美国国家科学基金会;
关键词
Solar cell; plasmonic; dye-sensitized; photovoltaic; solid-state; efficiency; OPTICAL-PROPERTIES; RELAXATION DYNAMICS; GOLD; PHOTOCURRENT; ENHANCEMENT; SIZE;
D O I
10.1021/nl1031106
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We present an investigation into incorporating core-shell Au-SiO2 nanoparticles into dye sensitized solar cells. We demonstrate plasmon-enhanced light absorption, photocurrent, and efficiency for both iodide/triiodide electrolyte based and solid-state dye-sensitized solar cells. Our spectroscopic investigation indicates that plasmon-enhanced photocarrier generation competes well with plasmons oscillation damping with in the first tens of femtoseconds following light absorption.
引用
收藏
页码:438 / 445
页数:8
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