Chiral effects on magnetic properties for chiral and racemic WV-CuII Prussian blue analogues

被引:45
作者
Higashikawa, Hiroyuki
Okuda, Kazuki
Kishine, Jun-ichiro
Masuhara, Naoji
Inoue, Katsuya [1 ]
机构
[1] Hiroshima Univ, Grad Sch Sci, Higashihiroshima 7398526, Japan
[2] Hiroshima Univ, Inst Adv Mat Res, Higashihiroshima 7398526, Japan
[3] Inst Mol Sci Inst, Dept Appl Mol Sci 1, Okazaki, Aichi 4448585, Japan
[4] Kyushu Inst Technol, Grad Sch Engn, Kitakyushu, Fukuoka 8048550, Japan
关键词
D O I
10.1246/cl.2007.1022
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The chiral and racemic 2-D antiferromagnets based on a cyano-bridged W-V-Cu-II compound are constructed. Both compounds are similar crystal structure, but some differences in magnetic proper-ties appear owing to the existence of the Dzyaloshinsky-Moriya (DM) interactions,(l) that is generated by crystal chirality.
引用
收藏
页码:1022 / 1023
页数:2
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