Fine structure transitions of BiOH in the near-infrared region

被引：6
|
作者：
Fink, EH
Shestakov, O
Setzer, KD
机构：
[1] Institute of Physics, St. Petersburg State University
[2] Physikalische Chemie, Fachbereich 9, Bergische Univ.-Gesamthochsch. W.
来源：
JOURNAL OF MOLECULAR SPECTROSCOPY | 1997年 / 183卷 / 01期
关键词：
D O I：
10.1006/jmsp.1997.7262
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
Near-infrared emission bands were observed near 6200 and 5700 cm(-1) when water vapor (H2O, D2O) was added to the reaction of bismuth vapor (Bi-x) with microwave-discharged oxygen in a fast-flow system. With the help of ab initio calculations of Yang Khandogin et al. (to be published in J. Mel. Spectrosc.) the bands were identified to be fine structure transitions (X) over tilde(2)A '' --> (X) over tilde(1)A' and (X) over tilde(3)A' --> (X) over tilde(1)A' between the components of the strongly split (3)A '' ground state of the as yet unknown bismuth hydroxide radical BiOH (BiOD). (C) 1997 Academic Press.
引用
收藏
页码：163 / 167
页数：5
相关论文
共 50 条
  • [1] SPECTRA-STRUCTURE CORRELATIONS FOR THE NEAR-INFRARED REGION
    GODDU, RF
    DELKER, DA
    ANALYTICAL CHEMISTRY, 1960, 32 (01) : 140 - 141
  • [2] Materials with electronic transitions in the near-infrared
    Wolfgang Kaim
    Journal of Chemical Sciences, 2019, 131
  • [3] Materials with electronic transitions in the near-infrared
    Kaim, Wolfgang
    JOURNAL OF CHEMICAL SCIENCES, 2019, 131 (09)
  • [4] Hyperfine structure and isotope shifts in near-infrared transitions of atomic nitrogen
    R. M. Jennerich
    A. N. Keiser
    D. A. Tate
    The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics, 2006, 40 : 81 - 89
  • [5] Electronic transitions of single silicon vacancy centers in the near-infrared spectral region
    Neu, Elke
    Albrecht, Roland
    Fischer, Martin
    Gsell, Stefan
    Schreck, Matthias
    Becher, Christoph
    PHYSICAL REVIEW B, 2012, 85 (24):
  • [6] Hyperfine structure and isotope shifts in near-infrared transitions of atomic nitrogen
    Jennerich, R. M.
    Keiser, A. N.
    Tate, D. A.
    EUROPEAN PHYSICAL JOURNAL D, 2006, 40 (01) : 81 - 89
  • [7] FINE-STRUCTURE OF NEAR-INFRARED OPTICAL-ABSORPTION IN NIO
    TSUBOI, T
    KLEEMANN, W
    JOURNAL OF PHYSICS-CONDENSED MATTER, 1994, 6 (41) : 8625 - 8631
  • [8] Holographic emulsion for the near-infrared region
    Petrova, T
    Popov, P
    Jordanova, E
    Sainov, S
    OPTICAL MATERIALS, 1996, 5 (03) : 193 - 195
  • [9] APPLICATIONS OF MICROSPECTROSCOPY IN THE NEAR-INFRARED REGION
    SMITH, MJ
    CARL, RT
    APPLIED SPECTROSCOPY, 1989, 43 (05) : 865 - 873
  • [10] NEAR-INFRARED ELECTRONIC-TRANSITIONS OF BIN
    BREIDOHR, R
    SETZER, KD
    SHESTAKOV, O
    FINK, EH
    ZYRNICKI, W
    JOURNAL OF MOLECULAR SPECTROSCOPY, 1994, 166 (02) : 471 - 485
12345