Ligand control in the photochemical generation of high-valent porphyrin-iron-oxo derivatives

被引：16

作者：

Chen, Tse-Hong ^{[1
]}

Asiri, Nawras ^{[1
]}

Kwong, Ka Wai ^{[1
]}

Malone, Jonathan ^{[1
]}

Zhang, Rui ^{[1
]}

机构：

[1] Western Kentucky Univ, Dept Chem, Bowling Green, KY 42101 USA

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 49期

基金：

美国国家科学基金会;

关键词：

FLASH-PHOTOLYSIS GENERATION; COMPOUND-I; ELECTRONIC-STRUCTURE; REACTIVITY; COMPLEXES; CORROLE;

D O I：

10.1039/c5cc02852c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Visible-light irradiation of photo-labile bromate porphyrin-iron(III) salts gave iron(IV)-oxo porphyrin radical cations (compound I model) or the neutral iron(IV)-oxo porphyrin (compound II model), depending on the electronic structure of porphyrin ligands.

引用

页码：9949 / 9952

页数：4

共 41 条

[1] ON PREPARATION OF METALLOPORPHYRINS [J].

ADLER, AD ;

LONGO, FR ;

KAMPAS, F ;

KIM, J .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1970, 32 (07) :2443-&

[2] A SIMPLIFIED SYNTHESIS FOR MESO-TETRAPHENYLPORPHIN [J].

ADLER, AD ;

LONGO, FR ;

FINARELLI, JD ;

GOLDMACH.J ;

ASSOUR, J ;

KORSAKOF.L .

JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (02) :476-+

[3] A High-Valent Iron-Oxo Corrolazine Activates C-H Bonds via Hydrogen-Atom Transfer [J].

Cho, Kevin ;

Leeladee, Pannee ;

McGown, Amanda J. ;

DeBeer, Serena ;

Goldberg, David P. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (17) :7392-7399

[4] PROBING STRUCTURE-FUNCTION RELATIONS IN HEME-CONTAINING OXYGENASES AND PEROXIDASES [J].

DAWSON, JH .

SCIENCE, 1988, 240 (4851) :433-439

[5]

de Visser SP, 2010, HANDB PORPHYR SCI, V10, P85

[6] Structure and chemistry of cytochrome P450 [J].

Denisov, IG ;

Makris, TM ;

Sligar, SG ;

Schlichting, I .

CHEMICAL REVIEWS, 2005, 105 (06) :2253-2277

[7] True Iron(V) and Iron(VI) porphyrins: A first theoretical exploration [J].

Dey, A ;

Ghosh, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (13) :3206-3207

[8] Differences and Comparisons of the Properties and Reactivities of Iron(III)-hydroperoxo Complexes with Saturated Coordination Sphere [J].

Faponle, Abayomi S. ;

Quesne, Matthew G. ;

Sastri, Chivukula V. ;

Banse, Frederic ;

de Visser, Sam P. .

CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (03) :1221-1236

[9] Electronic structure and reactivity of high-valent oxo iron porphyrins [J].

Fujii, H .

COORDINATION CHEMISTRY REVIEWS, 2002, 226 (1-2) :51-60

[10] EFFECTS OF THE ELECTRON-WITHDRAWING POWER OF SUBSTITUENTS ON THE ELECTRONIC-STRUCTURE AND REACTIVITY IN OXOIRON(IV) PORPHYRIN PI-CATION RADICAL COMPLEXES [J].

FUJII, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (11) :4641-4648

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