Large-scale delamination of multi-layers transition metal carbides and carbonitrides "MXenes"

被引：751

作者：

Naguib, Michael ^{[1
]}

Unocic, Raymond R. ^{[2
]}

Armstrong, Beth L. ^{[1
]}

Nanda, Jagjit ^{[1
]}

机构：

[1] Oak Ridge Natl Lab, Div Mat Sci & Technol, Oak Ridge, TN 37831 USA

[2] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 20期

关键词：

2-DIMENSIONAL TITANIUM CARBIDE; TI3C2X2; X; EXFOLIATION; NANOSHEETS; LI; INTERCALATION; GRAPHENE; ANODE; CAPACITANCE; CATALYST;

D O I：

10.1039/c5dt01247c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Herein we report on a general approach to delaminate multilayered MXenes using an organic base to induce swelling that in turn weakens the bonds between the MX layers. Simple agitation or mild sonication of the swollen MXene in water resulted in the large-scale delamination of the MXene layers. The delamination method is demonstrated for vanadium carbide and titanium carbonitride MXenes.

引用

页码：9353 / 9358

页数：6

共 37 条

[1]

Barsoum MW, 2013, MAX PHASES: PROPERTIES OF MACHINABLE TERNARY CARBIDES AND NITRIDES, P1, DOI 10.1002/9783527654581

[2] Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials [J].

Coleman, Jonathan N. ;

Lotya, Mustafa ;

O'Neill, Arlene ;

Bergin, Shane D. ;

King, Paul J. ;

Khan, Umar ;

Young, Karen ;

Gaucher, Alexandre ;

De, Sukanta ;

Smith, Ronan J. ;

Shvets, Igor V. ;

Arora, Sunil K. ;

Stanton, George ;

Kim, Hye-Young ;

Lee, Kangho ;

Kim, Gyu Tae ;

Duesberg, Georg S. ;

Hallam, Toby ;

Boland, John J. ;

Wang, Jing Jing ;

Donegan, John F. ;

Grunlan, Jaime C. ;

Moriarty, Gregory ;

Shmeliov, Aleksey ;

Nicholls, Rebecca J. ;

Perkins, James M. ;

Grieveson, Eleanor M. ;

Theuwissen, Koenraad ;

McComb, David W. ;

Nellist, Peter D. ;

Nicolosi, Valeria .

SCIENCE, 2011, 331 (6017) :568-571

[3] A Non-Aqueous Asymmetric Cell with a Ti2C-Based Two-Dimensional Negative Electrode [J].

Come, J. ;

Naguib, M. ;

Rozier, P. ;

Barsoum, M. W. ;

Gogotsi, Y. ;

Taberna, P. -L. ;

Morcrette, M. ;

Simon, P. .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2012, 159 (08) :A1368-A1373

[4] High capacitance of surface-modified 2D titanium carbide in acidic electrolyte [J].

Dall'Agnese, Yohan ;

Lukatskaya, Maria R. ;

Cook, Kevin M. ;

Taberna, Pierre-Louis ;

Gogotsi, Yury ;

Simon, Patrice .

ELECTROCHEMISTRY COMMUNICATIONS, 2014, 48 :118-122

[5] Ti3C2 MXene as a High Capacity Electrode Material for Metal (Li, Na, K, Ca) Ion Batteries [J].

Er, Dequan ;

Li, Junwen ;

Naguib, Michael ;

Gogotsi, Yury ;

Shenoy, Vivek B. .

ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (14) :11173-11179

[6] Preparation of MXene-Cu2O nanocomposite and effect on thermal decomposition of ammonium perchlorate [J].

Gao, Yupeng ;

Wang, Libo ;

Li, Zhengyang ;

Zhou, Aiguo ;

Hu, Qianku ;

Cao, Xinxin .

SOLID STATE SCIENCES, 2014, 35 :62-65

[7] Synthesis and characterization of two-dimensional Nb4C3 (MXene) [J].

Ghidiu, M. ;

Naguib, M. ;

Shi, C. ;

Mashtalir, O. ;

Pan, L. M. ;

Zhang, B. ;

Yang, J. ;

Gogotsi, Y. ;

Billinge, S. J. L. ;

Barsoum, M. W. .

CHEMICAL COMMUNICATIONS, 2014, 50 (67) :9517-9520

[8] Conductive two-dimensional titanium carbide 'clay' with high volumetric capacitance [J].

Ghidiu, Michael ;

Lukatskaya, Maria R. ;

Zhao, Meng-Qiang ;

Gogotsi, Yury ;

Barsoum, Michel W. .

NATURE, 2014, 516 (7529) :78-U171

[9] Transparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films [J].

Halim, Joseph ;

Lukatskaya, Maria R. ;

Cook, Kevin M. ;

Lu, Jun ;

Smith, Cole R. ;

Naslund, Lars-Ake ;

May, Steven J. ;

Hultman, Lars ;

Gogotsi, Yury ;

Eklund, Per ;

Barsoum, Michel W. .

CHEMISTRY OF MATERIALS, 2014, 26 (07) :2374-2381

[10] High-yield production of graphene by liquid-phase exfoliation of graphite [J].

Hernandez, Yenny ;

Nicolosi, Valeria ;

Lotya, Mustafa ;

Blighe, Fiona M. ;

Sun, Zhenyu ;

De, Sukanta ;

McGovern, I. T. ;

Holland, Brendan ;

Byrne, Michele ;

Gun'ko, Yurii K. ;

Boland, John J. ;

Niraj, Peter ;

Duesberg, Georg ;

Krishnamurthy, Satheesh ;

Goodhue, Robbie ;

Hutchison, John ;

Scardaci, Vittorio ;

Ferrari, Andrea C. ;

Coleman, Jonathan N. .

NATURE NANOTECHNOLOGY, 2008, 3 (09) :563-568

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