Enhancement of Photocatalytic Degradation of Poly(vinyl chloride) with Perchlorinated Iron (II) Phthalocyanine Modified Nano-TiO2

被引：25
作者：
Fa, Wenjun [1 ,2 ]
Gong, Chuqing [1 ]
Tian, Lihong [1 ]
Peng, Tianyou [1 ]
Zan, Ling [1 ]
机构：
[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China
[2] Xuchang Univ, Inst Surface Micro & Nano Mat, Xuchang 461000, Peoples R China
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2011年 / 122卷 / 03期
基金：
中国国家自然科学基金;
关键词：
poly(vinyl chloride); FePcCl16-TiO2; PVC-FePcCl16-TiO2 composite film; solid-phase photocatalytic degradation; VISIBLE-LIGHT; ORGANIC POLLUTANTS; TITANIUM-DIOXIDE; NANOCOMPOSITE FILM; TIO2; PVC; PHOTODEGRADATION; IRRADIATION; DYE; UV;
D O I：
10.1002/app.34230
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A novel photodegradable thin film of poly(vinyl chloride) (PVC) composite was prepared by embedding modified TiO2 nanoparticles into the commercial PVC. The photocatalyst nanoparticles were modified with perchlorinated iron (II) phthalocyanine (FePcCl16) to improve their photocatalytic activity. Solid-phase photocatalytic degradation of the PVC-FePcCl16-TiO2 thin film was carried out under ultraviolet (UV) lamp or sunlight irradiation in atmosphere. The properties of composite films were compared with those of pure PVC film and poly(vinyl chloride)-TiO2 (PVC-TiO2) composite films through performing weight loss monitoring, scanning electron microscope and Fourier-transform infrared spectroscopy. The results indicated that the degradation efficiency of PVC-FePcCl16-TiO2 composite film was significantly higher than that of pure PVC film and PVC-TiO2 composite film under UV or sunlight irradiation. The photocatalytic degradation mechanism was discussed briefly. (C) 2011 Wiley Periodicals, Inc. J Appl PolymSci 122: 1823-1828, 2011
引用
收藏
页码：1823 / 1828
页数：6
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