Stability studies of polypyrole- derived carbon based symmetric supercapacitor via potentiostatic floating test

被引：57

作者：

Bello, A. ^{[1
]}

Barzegar, F. ^{[1
]}

Madito, M. J. ^{[1
]}

Momodu, D. Y. ^{[1
]}

Khaleed, A. A. ^{[1
]}

Masikhwa, T. M. ^{[1
]}

Dangbegnon, J. K. ^{[1
]}

Manyala, N. ^{[1
]}

机构：

[1] Univ Pretoria, SARCHI Chair Carbon Technol & Mat, Inst Appl Mat, Dept Phys, ZA-0028 Pretoria, South Africa

来源：

ELECTROCHIMICA ACTA | 2016年 / 213卷

基金：

新加坡国家研究基金会;

关键词：

Polypyrole; activated carbon; supercapacitor; potentiostatic floating; aqueous electrolyte; RAMAN-SPECTROSCOPIC CHARACTERIZATION; CHEMICAL ACTIVATION; ELECTROLYTE; PERFORMANCE; CAPACITORS; NANOTUBES; NANODOTS; ENERGY;

D O I：

10.1016/j.electacta.2016.06.151

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

This work present the synthesis and electrochemical performance of mesoporous carbon material derived from the activation and carbonisation of polypyrole (PPY). Electrochemical performance of the PPY derived carbon was investigated in a two electrode cell in a 6 M KOH alkaline electrolyte. The symmetric device was subjected to floating test (voltage holding) for similar to 200 h at a voltage of 1.2 V and the specific capacitance as well as the resistance of device was determined after every 10 h of floating. The device exhibited a specific capacitance of 179 F g(-1) at 0.5 A g(-1) and 158 F g(-1) at 10 A g(-1). In addition, after floating for similar to 120 h the resistance was constant with a very slow decrease in capacitance. Beyond similar to 120 h, a quick decrease in capacitance was observed with a corresponding increase in resistance, indicating a possible deterioration to the electrodes. Remarkably, at the end of floating, the specific capacitance calculated at 5 A g(-1) was 120 F g(-1) (similar to 25% decay in capacitance from the initial value 160.5 F g(-1) at 5 A g(-1)) suggesting good stability of the device over a long period of time (similar to 8 days). (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：107 / 114

页数：8

共 43 条

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