Survey of temperature, reaction time and ultrasound irradiation power on sonochemical synthesis of two new nanostructured lead(II) coordination supramolecule compounds

Nanoparticles of two new OD, lead(II) coordination supramolecular compounds, [Pb(L)(2)(I)(2)] (1) and [Pb(L)(L-/)(H2O)center dot 3H(2)O (2), (L = 1,10-phenanthroline monohydrate, L-/ = 2,6-pyridinedicarboxlic acid), have been synthesized by a sonochemical process and characterized by scanning electron microscopy (SEM), field emission scanning electron microscopy (FE-SEM), X-ray powder diffraction (XRPD), FT-IR spectroscopy and elemental analyses. The single crystal X-ray data of compounds show that the Pb ion is six coordinated in both 1 and 2. The thermal stability of compound 1 and 2 has been studied by thermal gravimetric (TG) and differential thermal analyses (DTA). The role of temperature, reaction time and ultrasound irradiation power on the size and morphology of the nano-structured compound obtained from 1 and 2, have been investigated. Results indicate that an increase of temperature and sonication power and a decrease in time reaction led to a decrease of particle size. Topological analysis shows that the compound 1 and 2 are new topology for net: 1,4M5-1 and nch, respectively. (C) 2016 Elsevier B.V. All rights reserved.