Interrelation between H-bond and Pi-electron delocalization

被引：665

作者：

Sobczyk, L

Grabowski, SJ ^{[1
]}

Krygowski, TM

机构：

[1] Univ Lodz, Dept Crystallog & Crystal Chem, Pomorska 149-153, PL-90236 Lodz, Poland

[2] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

[3] Univ Warsaw, Dept Chem, PL-02093 Warsaw, Poland

来源：

CHEMICAL REVIEWS | 2005年 / 105卷 / 10期

关键词：

D O I：

10.1021/cr030083c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An overview is given of the relationship between H-bond and pi-electron delocalization. Hydrogen atom is associated with electron delocalization in terms of location and its interactions with both neighboring atoms. The H-bond may be associated with cooperative interactions discussed in terms of the resonance-assisted H-bond, which lead to π-electron delocalization of distand bonds built of atoms bearing π electrons. The changes of these parameters are associated with the changes in charge distribution in the region of the H-bond. Phenomena are revealed in the AIM and aromacity parameters as well as C NMR chemical shifts.

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页码：3513 / 3560

页数：48

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