Construction of 3d-4f heterometallic coordination polymers by simultaneous use of hexacyanometalate building-blocks and exo-bidentate ligands

被引：92

作者：

Tanase, S

Andruh, M

Müller, A

Schmidtmann, M

Mathonière, C

Rombaut, G

机构：

[1] Univ Bucharest, Fac Chem, Inorgan Chem Lab, Bucharest 70254, Romania

[2] Univ Bielefeld, Fak Chem, D-33501 Bielefeld, Germany

[3] Inst Chim Mat Condensee Bordeaux, Lab Sci Mol, F-33608 Pessac, France

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 12期

关键词：

D O I：

10.1039/b101070k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of Pr(NO3)(3) 6H(2)O with 4,4'-bipyridine N,N'-dioxide (L) and K-3[M(CN)(6)] [M Fe-III, Co-III] gives isomorphous heteropolynuclear complexes with formula [{(H2O)(5)LPr-NC-M(CN)(5)}(mu -L)].0.5L.4H(2)O, which exhibit a novel supramolecular architecture created by the interplay of coordinative, hydrogen bonding and pi-pi stacking interactions.

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页码：1084 / 1085

页数：2

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