Comparative corrosion behavior of Zn with Fe and Mg in the course of immersion degradation in phosphate buffered saline

被引:132
作者
Chen, Yingqi [1 ]
Zhang, Wentai [1 ]
Maitz, Manfred F. [1 ,2 ]
Chen, Meiyun [1 ]
Zhang, Heng [1 ]
Mao, Jinlong [1 ]
Zhao, Yuancong [1 ]
Huang, Nan [1 ]
Wan, Guojiang [1 ]
机构
[1] Southwest Jiaotong Univ, Coll Mat Sci & Engn, Key Lab Adv Technol Mat, Minist Educ, Chengdu 61003, Peoples R China
[2] Max Bergmann Ctr Biomat, Leibniz Inst Polymer Res Dresden, Hohe Str 06, D-01069 Dresden, Germany
基金
中国国家自然科学基金;
关键词
Zinc; Iron; Magnesium; Oxygen reduction; Pitting corrosion; Kinetic parameters; BIODEGRADABLE MAGNESIUM IMPLANTS; IN-VITRO DEGRADATION; PITTING CORROSION; PURE IRON; ALLOYS; ZINC; OXIDATION; STENTS; RESISTANCE; COATINGS;
D O I
10.1016/j.corsci.2016.05.039
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The corrosion behavior of Zn was compared with those of Fe and Mg in a long-term course of immersing in phosphate buffered saline (PBS) as biodegradable metal for bio-implants application. The comparison focused on corrosion rate, mode, products and surface characteristics along the immersion degradation up to 21 days. For transient assays, the open circuit potential and corrosion rate placed Zn between Fe and Mg. However, in a long-term course the corrosion rate of Zinc developed faster than Fe and Mg. This was ascribed to its unique localized corrosion and corrosion products changing in contrast to Fe and Mg. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:541 / 555
页数:15
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