Promoting Methane Hydrate Formation for Natural Gas Storage over Chabazite Zeolites

被引：26
作者：
Denning, Shurraya [1 ]
Majid, Ahmad A. A. [1 ]
Crawford, James M. [1 ]
Carreon, Moises A. [1 ]
Koh, Carolyn A. [1 ]
机构：
[1] Colorado Sch Mines, Chem & Biol Engn Dept, Golden, CO 80401 USA
来源：
ACS APPLIED ENERGY MATERIALS | 2021年 / 4卷 / 12期
基金：
美国国家科学基金会;
关键词：
gas hydrates; chabazite zeolites; gas storage; natural gas; hydrophobicity; hydrate promoter; SAPO-34; MEMBRANES; SSZ-13; CH4; CO2;
D O I：
10.1021/acsaem.1c02902
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Gas hydrates are a promising methane storage method. This study investigates the potential for zeolites to overcome hydrate formation limitations. The chabazite zeolites SSZ-13 and SAPO-34 increased water-to-hydrate conversion from 5.8 +/- 1.4% to 91.3 +/- 0.5% and 38.4 +/- 1.5%, respectively, due to the high surface area of the zeolites enlarging the gas-to-water contact area. SSZ-13 promoted on average 2.6 times more hydrate growth than SAPO-34 due to SSZ-13's more hydrophobic nature resulting in higher methane adsorption (can be consumed in hydrate formation) and lower electrostaticity (does not restrict water activity/orientation). Overall, SSZ-13 maintains its structural integrity and exhibits reproducible hydrate formation promotion results.
引用
收藏
页码：13420 / 13424
页数：5
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