Improvement in the leakage current characteristic of metal-insulator-metal capacitor by adopting RuO2 film as bottom electrode

被引:73
作者
Han, Jeong Hwan [1 ,2 ]
Han, Sora [1 ,2 ]
Lee, Woongkyu [1 ,2 ]
Lee, Sang Woon [1 ,2 ]
Kim, Seong Keun [1 ,2 ]
Gatineau, Julien [3 ]
Dussarrat, Christian [3 ]
Hwang, Cheol Seong [1 ,2 ]
机构
[1] Seoul Natl Univ, WCU Hybrid Mat Program, Dept Mat Sci & Engn, Seoul 151744, South Korea
[2] Seoul Natl Univ, Interuniv Semicond Res Ctr, Seoul 151744, South Korea
[3] Air Liquide, Tsukuba, Ibaraki, Japan
基金
新加坡国家研究基金会;
关键词
CHEMICAL-VAPOR-DEPOSITION; ATOMIC-LAYER DEPOSITION; DOPED TIO2 FILMS; THIN-FILMS; GROWTH; PRECURSOR; OXIDE;
D O I
10.1063/1.3609875
中图分类号
O59 [应用物理学];
学科分类号
摘要
The dielectric constant, equivalent oxide thickness (t(ox)), and leakage current properties of Pt/(Al-doped) TiO2/RuO2 capacitors were examined in comparison with Pt/(Al-doped) TiO2/Ru capacitors. The Al-doped TiO2 and undoped TiO2 films grown on RuO2 showed high dielectric constants of 60 and 102, respectively. The minimum tox of these films were 0.46 nm and 0.56 nm, respectively, while still satisfying the dynamic random access memory leakage current density specification (< 1 x 10(-7) Acm(-2) at capacitor voltage of 0.8 V). These excellent electrical properties of (Al-doped) TiO2 on RuO2 were attributed to the high work function and the reduced interfacial effect on RuO2. (C) 2011 American Institute of Physics. [doi: 10.1063/1.3609875]
引用
收藏
页数:3
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共 10 条
[1]   Plasma-Enhanced Atomic Layer Deposition of TiO2 and Al-Doped TiO2 Films Using N2O and O2 Reactants [J].
Choi, Gyu-Jin ;
Kim, Seong Keun ;
Won, Seok-Jun ;
Kim, Hyeong Joon ;
Hwang, Cheol Seong .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (09) :G138-G143
[2]   Growth of high-dielectric-constant TiO2 films in capacitors with RuO2 electrodes [J].
Frohlich, K. ;
Tapajna, M. ;
Rosova, A. ;
Dobrocka, E. ;
Husekova, K. ;
Aarik, J. ;
Aidla, A. .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2008, 11 (06) :G19-G21
[3]   Growth of RuO2 Thin Films by Pulsed-Chemical Vapor Deposition Using RuO4 Precursor and 5% H2 Reduction Gas [J].
Han, Jeong Hwan ;
Lee, Sang Woon ;
Kim, Seong Keun ;
Han, Sora ;
Hwang, Cheol Seong ;
Dussarrat, Christian ;
Gatineau, Julien .
CHEMISTRY OF MATERIALS, 2010, 22 (20) :5700-5706
[4]   Chemical Vapor Deposition of Ru Thin Films with an Enhanced Morphology, Thermal Stability, and Electrical Properties Using a RuO4 Precursor [J].
Han, Jeong Hwan ;
Lee, Sang Woon ;
Choi, Gyu-Jin ;
Lee, Sang Young ;
Hwang, Cheol Seong ;
Dussarrat, Christian ;
Gatineau, Julien .
CHEMISTRY OF MATERIALS, 2009, 21 (02) :207-209
[5]   Ruthenium oxide and strontium ruthenate electrodes for ferroelectric thin-films capacitors [J].
Hartmann, AJ ;
Neilson, M ;
Lamb, RN ;
Watanabe, K ;
Scott, JF .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2000, 70 (02) :239-242
[6]   Al-doped TiO2 films with ultralow leakage currents for next generation DRAM capacitors [J].
Kim, Seong Keun ;
Choi, Gyu-Jin ;
Lee, Sang Young ;
Seo, Minha ;
Lee, Sang Woon ;
Han, Jeon Hwan ;
Ahn, Hyo-Shin ;
Han, Seungwu ;
Hwang, Cheol Seong .
ADVANCED MATERIALS, 2008, 20 (08) :1429-+
[7]   Capacitors with an Equivalent Oxide Thickness of &lt;0.5 nm for Nanoscale Electronic Semiconductor Memory [J].
Kim, Seong Keun ;
Lee, Sang Woon ;
Han, Jeong Hwan ;
Lee, Bora ;
Han, Seungwu ;
Hwang, Cheol Seong .
ADVANCED FUNCTIONAL MATERIALS, 2010, 20 (18) :2989-3003
[8]   High dielectric constant TiO2 thin films on a Ru electrode grown at 250 °C by atomic-layer deposition [J].
Kim, SK ;
Kim, WD ;
Kim, KM ;
Hwang, CS ;
Jeong, J .
APPLIED PHYSICS LETTERS, 2004, 85 (18) :4112-4114
[9]   Band offsets of high K gate oxides on III-V semiconductors [J].
Robertson, J. ;
Falabretti, B. .
JOURNAL OF APPLIED PHYSICS, 2006, 100 (01)
[10]   Low Temperature Epitaxial Growth of High Permittivity Rutile TiO2 on SnO2 [J].
Wang, Hongtao ;
Xu, Sheng ;
Gordon, Roy G. .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2010, 13 (09) :G75-G78