Row nucleation phenomenon of Poly(phenylene sulfide) under shear condition

被引:5
作者
Zhang, Richao [1 ]
Min, Min [1 ]
Gao, Yong [1 ]
Lu, Ai [1 ,2 ]
Yu, Xuejiang [2 ]
Huang, Yigang [2 ]
Lu, Zhongyuan [1 ]
机构
[1] SW Univ Sci & Technol, Coll Mat Sci & Engn, Sichuan 621002, Peoples R China
[2] China Acad Engn Phys, Inst Chem Mat, Sichuan 621900, Peoples R China
关键词
poly(phenylene sulfide); shear; spherulite;
D O I
10.1016/j.matlet.2007.08.075
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The crystalline morphology of Poly(phenylene sulfide) (PPS) isothermally crystallized from the melt under shear conditions has been investigated by polarized optical microscope (POM) equipped with a CSS450 hot stage. The crystalline morphology of PPS is mainly spherulite and greatly influenced by shear flow field. That is, the shear can cause these spherulite orientations, and the row nucleation structure occurs under shear flow conditions. We ascribe it to the tight aggregation of numerous nuclei in the direction of shear. (C) 2007 Published by Elsevier B.V.
引用
收藏
页码:1414 / 1417
页数:4
相关论文
共 44 条
[1]  
[Anonymous], PROCESSING POLYM
[2]  
Bove L, 2002, MACROMOL SYMP, V185, P135, DOI 10.1002/1521-3900(200208)185:1<135::AID-MASY135>3.0.CO
[3]  
2-S
[4]   THERMAL-ANALYSIS OF POLY(PHENYLENE SULFIDE) .2. NONISOTHERMAL CRYSTALLIZATION [J].
COLLINS, GL ;
MENCZEL, JD .
POLYMER ENGINEERING AND SCIENCE, 1992, 32 (17) :1270-1277
[5]   Microrheological modeling of flow-induced crystallization [J].
Coppola, S ;
Grizzuti, N ;
Maffettone, PL .
MACROMOLECULES, 2001, 34 (14) :5030-5036
[6]   Langevin dynamics simulations of early stage shish-kebab crystallization of polymers in extensional flow [J].
Dukovski, I ;
Muthukumar, M .
JOURNAL OF CHEMICAL PHYSICS, 2003, 118 (14) :6648-6655
[7]   Crystallization in isotactic polypropylene melts during contraction flow:: time-resolved synchrotron WAXD studies [J].
Göschel, U ;
Swartjes, FHM ;
Peters, GWM ;
Meijer, HEH .
POLYMER, 2000, 41 (04) :1541-1550
[8]  
HARTNESS JT, 1980, 25 NATL SAMPE S EXH, P376
[9]   PROPERTIES, ENVIRONMENTAL STABILITY, AND MOLDING CHARACTERISTICS OF POLYPHENYLENE SULFIDE [J].
HILL, HW ;
BRADY, DG .
POLYMER ENGINEERING AND SCIENCE, 1976, 16 (12) :831-835
[10]   FURTHER STUDIES ON POLYETHYLENE CRYSTALLIZED UNDER STRESS - MORPHOLOGY, CALORIMETRY, AND STRESS RELAXATION [J].
HILL, MJ ;
KELLER, A .
JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, 1971, B 5 (03) :591-&