N-Heterocyclic Carbene-Catalyzed [2+2+2] Annulation of Allenoates with Trifluoromethylketones

被引：36
作者：
Sun Lihui [1 ]
Wang Tong [1 ]
Ye Song [1 ]
机构：
[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2012年 / 30卷 / 01期
关键词：
NHC-catalyzed; 2+2+2] annulations; allenoates; trifluoromethylketones; ELECTRON-DEFICIENT OLEFINS; BAYLIS-HILLMAN REACTION; ONE-POT SYNTHESIS; 3+2 CYCLOADDITION; ALLENIC ESTERS; NUCLEOPHILIC CARBENES; PHOSPHINE; ALDEHYDES; IMINES; KETONES;
D O I：
10.1002/cjoc.201100383
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In contrast with the reported phosphine- and DABCO-catalyzed [3+2] and [2+2] annulation of allenoates with trifluoromethylketone, the [2+2+2] annulation of allenoates and two molecules of trifluoromethylketone was found under the condition of N-heterocyclic carbene catalysis.
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页码：190 / 194
页数：5
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