Bimetallic complexes in artificial photosynthesis for hydrogen production: A review

被引：46

作者：

Arifin, Khuzaimah ^{[1
,2
]}

Majlan, Edy Herianto ^{[1
]}

Daud, Wan Ramli Wan ^{[1
,2
]}

Kassim, Mohammad B. ^{[1
,3
]}

机构：

[1] Univ Kebangsaan Malaysia, Fuel Cell Inst, Ukm Bangi 43600, Selangor, Malaysia

[2] Univ Kebangsaan Malaysia, Dept Chem & Proc Engn, Ukm Bangi 43600, Selangor, Malaysia

[3] Univ Kebangsaan Malaysia, Sch Sci & Food Technol, Fac Sci & Technol, Ukm Bangi 43600, Selangor, Malaysia

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2012年 / 37卷 / 04期

关键词：

Artificial photosynthesis; Photosensitizer; Bimetallic complex; Electron transfer; Energy transfer; INTRAMOLECULAR ELECTRON-TRANSFER; RUTHENIUM-MANGANESE COMPLEXES; SOLAR-ENERGY CONVERSION; VISIBLE-LIGHT; PHOTOINDUCED ELECTRON; ELECTROCHEMICAL-BEHAVIOR; PHOTOCHEMICAL CONVERSION; PHOTOPHYSICAL PROPERTIES; POLYPYRIDINE COMPLEXES; DINUCLEAR RU(II);

D O I：

10.1016/j.ijhydene.2011.11.052

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Artificial photosynthesis technology is a solar energy conversion technology that mimics natural photosynthesis mainly for hydrogen production. There are two systems in artificial photosynthesis technology: (i) Homogeneous system that mimics the electron transfer steps of water (via manganese) in natural photosynthesis and (ii) Heterogeneous system, for example, dye-sensitized photoelectrochemical solar cell system. Transition metal complexes are used in these systems to harness light, and the complexes serve as catalysts as well as the reaction center. Various efforts have been made to increase the efficiency of both systems. Currently, homo- and heterobimetallic complexes are among the molecules that have been investigated. Intramolecular energy transfer in the bimetallic complexes is predicted to improve the lifetime of interfacial charge and power output of solar cells. This review summarizes bimetallic molecules that have been investigated for use in artificial photosynthesis, including the mechanisms of electron and energy transfer as well as the function and role of each component in the bimetallic molecules. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：3066 / 3087

页数：22

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