Facile Fabrication of Radial PtCo Nanodendrites for Enhanced Methanol Oxidation Electrocatalysis

被引:33
作者
Huang, Lei [1 ]
Jiang, Zheng [1 ]
Gong, Wenhao [1 ]
Shen, Pei Kang [1 ]
机构
[1] Guangxi Univ, State Key Lab Proc Nonferrous Met & Featured Mat, Collaborat Innovat Ctr Sustainable Energy Mat, Guangxi Key Lab Electrochem Energy Mat, Nanning 530004, Peoples R China
来源
ACS APPLIED NANO MATERIALS | 2018年 / 1卷 / 09期
关键词
one-step; methanol oxidation reaction; radial; modified solvothermal; tip areas; OXYGEN REDUCTION REACTION; HIGH-INDEX FACETS; CONCAVE NANOCUBES; CATALYTIC PERFORMANCE; PLATINUM; ALLOY; NANOPARTICLES; CORE; CU; NANOWIRES;
D O I
10.1021/acsanm.8b01113
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
To improve the catalytic performances of Pt-based catalysts toward the methanol oxidation reaction (MOR) and reduce the consumption of Pt, we report one-step facile fabrication of radial PtCo nanodendrites (NDs) by a modified solvothermal method. It is noticeable that the radial PtCo NDs have a Pt-rich surface, and the radial PtCo NDs possess more tip areas due to unique first level NDs and more interconnected second level NDs, which can facilitate electronic transmission and mass exchange. Compared with commercial Pt/C, the radial PtCo NDs catalyst shows enhanced catalytic performance and stability toward the MOR. More importantly, this study offers more opportunities to prepare bimetallic NDs with enhanced catalytic performance.
引用
收藏
页码:5019 / 5026
页数:15
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