A Porous 4d-4f Heterometallic Coordination Polymer: Synthesis, Crystal Structure and Physical Properties

被引：3

作者：

Liu, Guang-Xiang ^{[1
]}

Li, Xin-Long ^{[1
]}

Zha, Xiao-Chun ^{[1
]}

Zhang, Chun-You ^{[1
]}

Wang, Yan ^{[1
]}

Ren, Xiao-Ming ^{[1
]}

机构：

[1] Anqing Normal Univ, Sch Chem & Chem Engn, Anhui Key Lab Funct Coordinat Cpds, Anqing 246003, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2011年 / 637卷 / 11期

基金：

中国国家自然科学基金;

关键词：

Heterometallic coordination polymer; Porous materials; Silver; Lanthanum; Gas adsorption; O-DONOR LIGANDS; MAGNETIC-PROPERTIES; ASYMMETRIC CATALYSIS; LANTHANIDE COMPLEXES; METAL-COMPLEXES; N-DONOR; 3D; FRAMEWORKS; ACID; LUMINESCENCE;

D O I：

10.1002/zaac.201100141

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 4d-4f heterometallic coordination polymer, [AgLa(pydc)(2)]center dot 3H(2)O (1) (H(2)pydc = pyridine-3,4-dicarboxylic acid), has been synthesized under hydrothermal conditions, and further characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis and single-crystal X-ray diffraction. Complex 1 features a three-dimensional (3D) framework containing one-dimensional (1D) channels occupied by free water molecules, which is constructed from 1D inorganic heterometallic chains and linear pydc linkers. To the best of our knowledge, complex 1 represents a rare example of 3D open-framework 4d-4f heterometallic coordination polymer. Moreover, after removal of the water molecules from complex 1, the remaining material has high thermal stability and good adsorption behavior towards nitrogen gas.

引用

页码：1555 / 1559

页数：5

共 42 条

[1] Synthesis and structure of the two-dimensional coordination networks [Ln(PDQ(N-HPDC)]∞ (PDC = pyridine-3,4-dicarboxylate, Ln = La, Ce, Pr)
Ang, Desmond
Deacon, Glen B.
Junk, Peter C.
Turner, David R.
[J]. POLYHEDRON, 2007, 26 (02) : 385 - 391
[2] [Anonymous], 2002, SAINT VERS 6 02A
[3] CRYSTAL AND MOLECULAR-STRUCTURE OF AND MAGNETIC COUPLING IN 2 COMPLEXES CONTAINING GADOLINIUM(III) AND COPPER(II) IONS
BENCINI, A
BENELLI, C
CANESCHI, A
CARLIN, RL
DEI, A
GATTESCHI, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (26) : 8128 - 8136
[4] BIS(PENTAMETHYLCYCLOPENTADIENYL)YTTERBIUM(II) AS A LEWIS ACID AND ELECTRON-TRANSFER LIGAND - PREPARATION AND CRYSTAL-STRUCTURES OF [YB(ME5C5)2(MU-CO)XMN(CO)5-X]Y (X,Y=2 X=3,Y= INFINITY
BONCELLA, JM
ANDERSEN, RA
[J]. INORGANIC CHEMISTRY, 1984, 23 (04) : 432 - 437
[5] Preparation of resolved fourfold symmetric amphiphilic helices using chiral metallacrown building blocks
Cutland-Van Noord, AD
Kampf, JW
Pecoraro, VL
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2002, 41 (24) : 4667 - 4670
[6] Self-assembly of {Ag2N4}-core-containing coordination polymers from AgX (X=NO3-, ClO4-, and PF6-) and oxadiazole-bridged 4,4′- and 3,3′-biphenylamine Ligands
Dong, YB
Cheng, JY
Ma, JP
Huang, RQ
[J]. CRYSTAL GROWTH & DESIGN, 2005, 5 (02) : 585 - 591
[7] Incorporating metal clusters into three-dimensional Ln(III)-Cu(I) coordination frameworks through linear Ligands
Gu, Xiaojun
Xue, Dongfeng
[J]. CRYSTAL GROWTH & DESIGN, 2007, 7 (09) : 1726 - 1732
[8] Self-assembly of 3-D 4d-4f coordination frameworks based on 1-D inorganic heterometallic chains and linear organic linkers
Gu, Xiaojun
Xue, Dongfeng
[J]. CRYSTENGCOMM, 2007, 9 (06): : 471 - 477
[9] Spontaneously resolved homochiral 3D lanthanide-silver heterometallic coordination framework with extended helical Ln-O-Ag subunits
Gu, Xiaojun
Xue, Dongfeng
[J]. INORGANIC CHEMISTRY, 2006, 45 (23) : 9257 - 9261
[10] Selected controlled synthesis of three-dimensional 4d-4f heterometallic coordination frameworks by lanthanide carboxylate subunits and silver centers
Gu, Xiaojun
Xue, Dongfeng
[J]. CRYSTAL GROWTH & DESIGN, 2006, 6 (11) : 2551 - 2557

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