Selective electrochemical fluorination of organic molecules and macromolecules in ionic liquids

被引：114

作者：

Fuchigami, Toshio ^{[1
]}

Inagi, Shinsuke ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 37期

关键词：

ELECTROLYTIC PARTIAL FLUORINATION; REGIOSELECTIVE ANODIC MONOFLUORINATION; OXIDATIVE FLUORINATION; AROMATIC-COMPOUNDS; HYDROGEN-FLUORIDE; ENANTIOSELECTIVE FLUORINATION; POST-FUNCTIONALIZATION; ALTERNATING COPOLYMER; ALIPHATIC-ALDEHYDES; VINYL SULFIDES;

D O I：

10.1039/c1cc12414e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This article provides an outline of recent studies on selective electrochemical fluorination in ionic liquid fluoride salts toward green sustainable chemistry. First, a brief historical background of electrochemical fluorination in organic solvents is provided, and some particular problems and unique solvent effects associated with this technique are briefly mentioned. Second, recent progress in selective fluorination and fluorodesulfurization of organic molecules and macromolecules in ionic liquids using direct and indirect electrolysis with recyclable mediators is reviewed.

引用

页码：10211 / 10223

页数：13

共 118 条

[1] Anodic fluorination of vinyl sulfides-synthesis of alpha-fluoro-beta-thio-alpha,beta-unsaturated carbonyl compounds [J].