Microcrystalline/micromorph silicon thin-film solar cells prepared by VHF-CD technique

被引:121
作者
Meier, J [1 ]
Vallat-Sauvain, E [1 ]
Dubail, S [1 ]
Kroll, U [1 ]
Dubail, J [1 ]
Golay, S [1 ]
Feitknecht, L [1 ]
Torres, P [1 ]
Fay, S [1 ]
Fischer, D [1 ]
Shah, A [1 ]
机构
[1] Univ Neuchatel, Inst Microtech, CH-2000 Neuchatel, Switzerland
关键词
hydrogenated microcrystalline silicon; thin-film crystalline silicon; VHF-GD; micromorph concept; monolithic series connection;
D O I
10.1016/S0927-0248(00)00160-4
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Hydrogenated microcrystalline silicon prepared at low temperatures by the glow discharge technique is examined here with respect to its role as a new thin-him photovoltaic absorber material. XRD and TEM characterisations reveal that microcrystalline silicon is a semiconductor with a very complex morphology. Microcrystalline p-i-n cells with open-circuit voltages of up to 560-580 mV could be prepared. "Micromorph" tandem solar cells show under outdoor conditions higher short-circuit currents due to the enhanced blue spectra of real sun light and therefore higher efficiencies than under AM1.5 solar simulator conditions. Furthermore, a weak air mass dependence of the short-circuit current density could be observed for such micromorph tandem solar cells. By applying the monolithic series connection based on laser patterning a first micromorph mini-module (total area of 23.6 cm(2)) with 9% cell conversion efficiency could be fabricated. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
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页码:73 / 84
页数:12
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