Preparation of a starch-based adhesive cross-linked with furfural, furfuryl alcohol and epoxy resin

被引：30
作者：
Zhang, Jun [1 ]
Liu, Bowen [1 ]
Zhou, Yunxia [1 ]
Essawy, Hisham [3 ]
Chen, Qian [2 ]
Zhou, Xiaojian [1 ]
Du, Guanben [1 ]
机构：
[1] Southwest Forestry Univ, Yunnan Key Lab Wood Adhes & Glued Prod, Kunming 650224, Yunnan, Peoples R China
[2] Southwest Forestry Univ, Key Lab State Forestry & Grass & Adm Highly Effic, Kunming 650224, Yunnan, Peoples R China
[3] Natl Res Ctr, Dept Polymers & Pigments, Cairo 12622, Egypt
来源：
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES | 2021年 / 110卷
关键词：
Enhanced starch adhesive; Furfural; Furfuryl alcohol; Cross-linking; Epoxy resin; GRAFT-COPOLYMERIZATION; TANNIN/FURANIC FOAMS; WOOD ADHESIVE; ACID; PERFORMANCE; CONVERSION; GLYOXAL;
D O I：
10.1016/j.ijadhadh.2021.102958
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Furfural and furfuryl alcohol originating from agriculture were used as crosslinkers to develop a renewable starch-furanic adhesive with good water resistance. Electrospray ionization mass spectroscopy and C-13 nuclear magnetic resonance measurements indicated that furfural and furfuryl alcohol reacted with starch under acidic conditions and that the -CH2-O- groups were involved in the cross-linking of the starch-furfural-furfuryl alcohol adhesive (SFF). The gel time of SFF was longer than that of the starch-furfural adhesive (SF), while the dry shear strength of the SFF-bonded plywood suggested that the cured SFF adhesive acquired a performance better than that of starch (S) and SF adhesives. Moreover, the water resistance of the SFF adhesive cross-linked with 9% epoxy resin was further enhanced with respect to that of the S, SF, and commercial phenol formaldehyde adhesives.
引用
收藏
页数：11
相关论文
共 30 条
[1]  
Abdullah UHB, 2013, EUR J WOOD WOOD PROD, V71, P131, DOI 10.1007/s00107-012-0629-4
[2]   Diels-Alder reactions between hexafluoro-2-butyne and bis-furyl dienes: kinetic versus thermodynamic control [J].
Borisova, Kseniya K. ;
Nikitina, Eugeniya V. ;
Novikov, Roman A. ;
Khrustalev, Victor N. ;
Dorovatovskii, Pavel V. ;
Zubavichus, Yan V. ;
Kuznetsov, Maxim L. ;
Zaytsev, Vladimir P. ;
Varlamov, Alexey V. ;
Zubkov, Fedor I. .
CHEMICAL COMMUNICATIONS, 2018, 54 (23) :2850-2853
[3]   Mechanical properties of tannin-based rigid foams undergoing compression [J].
Celzard, A. ;
Zhao, W. ;
Pizzi, A. ;
Fierro, V. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2010, 527 (16-17) :4438-4446
[4]   Enhancing the performance of starch-based wood adhesive by silane coupling agent(KH570) [J].
Chen, Lei ;
Wang, Yajie ;
Zia-ud-Din ;
Fei, Peng ;
Jin, Wensi ;
Xiong, Hanguo ;
Wang, Zhenjiong .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2017, 104 :137-144
[5]   Direct conversion of starch to hydroxymethylfurfural in the presence of an ionic liquid with metal chloride [J].
Chun, Jae-An ;
Lee, Jin-Woo ;
Yi, Young-Byung ;
Hong, Seong-Sig ;
Chung, Chung-Han .
STARCH-STARKE, 2010, 62 (06) :326-330
[6]   Starch-graft-(synthetic copolymer) latexes initiated with Ce4+ and stabilized by amylopectin [J].
De Bruyn, Hank ;
Sprong, Ewan ;
Gaborieau, Marianne ;
Roper, John A., III ;
Gilbert, Robert G. .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2007, 45 (18) :4185-4192
[7]  
Din Z, 2017, COLLOID SURFACE PHYS, V11
[8]   In situ polymerization of starch with lactic acid in aqueous solution and the microstructure characterization [J].
Gong, Qingxia ;
Wang, Li-Qun ;
Tu, Kehua .
CARBOHYDRATE POLYMERS, 2006, 64 (04) :501-509
[9]   Chemorheological analysis and model-free kinetics of acid catalysed furfuryl alcohol polymerization [J].
Guigo, Nathanael ;
Mija, Alice ;
Vincent, Luc ;
Sbirrazzuoli, Nicolas .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (39) :5359-5366
[10]   Effect of Phenolic Resin Oligomer Motion Ability on Energy Dissipation of Poly (Butyl Methacrylate)/Phenolic Resins Composites [J].
Huang, Xing ;
Chen, Songbo ;
Wan, Songhan ;
Niu, Ben ;
He, Xianru ;
Zhang, Rui .
POLYMERS, 2020, 12 (02)
123