Real-Time Molecular-Scale Imaging of Dynamic Network Switching between Covalent Organic Frameworks

被引：58

作者：

Zhan, Gaolei ^{[1
]}

Cai, Zhen-Feng ^{[1
]}

Martinez-Abadia, Marta ^{[2
]}

Mateo-Alonso, Aurelio ^{[2
,3
]}

De Feyter, Steven ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Div Mol Imaging & Photon, Dept Chem, B-3001 Leuven, Belgium

[2] Univ Basque Country, POLYMAT, UPV EHU, Donostia San Sebastian 20018, Spain

[3] Basque Fdn Sci, Ikerbasque, Bilbao 48013, Spain

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2020年 / 142卷 / 13期

关键词：

CONSTRUCTION; CRYSTALLINE; EXCHANGE; MODULATION; REDUCTION; CHEMISTRY; LIGHT;

D O I：

10.1021/jacs.0c01270

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The in situ on-surface conversion process from boroxine-linked covalent organic frameworks (COFs) to boronate ester-linked COFs is triggered and catalyzed at room temperature by an electric field and monitored with scanning tunneling microscopy (STM). The adaptive behavior within the generated dynamic covalent libraries (DCLs) was revealed, providing in-depth understanding of the dynamic network switching process.

引用

页码：5964 / 5968

页数：5

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