Ultrafine SnO2 nanocrystals anchored graphene composites as anode material for lithium-ion batteries

被引:31
作者
Zhang, Jun [1 ]
Chang, Ling
Wang, Fengxian
Xie, Dong
Su, Qingmei
Du, Gaohui
机构
[1] Zhejiang Normal Univ, Inst Phys Chem, Key Lab Minist Educ Adv Catalysis Mat, Jinhua 321004, Peoples R China
基金
中国国家自然科学基金;
关键词
Nanostructures; Composites; Solvothermal; Electrochemical properties; SNO2/GRAPHENE NANOCOMPOSITES; ELECTROCHEMICAL PERFORMANCE; STORAGE PROPERTIES; CARBON NANOTUBES; OXIDE; TIN; SHELL; MICROSTRUCTURE; ELECTRODES; LITHIATION;
D O I
10.1016/j.materresbull.2015.03.041
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Ultrafine tin dioxide (SnO2) nanocrystals anchored graphene composite is synthesized by a simple hydrothermal method. Well-defined SnO2 nanocrystals with size of 5 nm are uniformly anchored on the graphene sheets. The two-dimensional nanostructure inherits the advantages of graphene, which possesses high electrical conductivity and large surface area. Furthermore, the ultrafine SnO2 nanocrystals anchoring on graphene sheets facilitate fast ion transportation and prevent aggregation. As a result, the produced nanocomposite exhibits an excellent cycling stability and rate capability for lithium storage (808 mAh g(-1) after 100 cycles at 200 mA g(-1), 1290 mAh g(-1) at the current of 50 mA g(-1) after being cycled at various current densities for 60 cycles). (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:120 / 125
页数:6
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