Oxidatively Stable, Aqueous Europium(II) Complexes through Steric and Electronic Manipulation of Cryptand Coordination Chemistry

被引：79

作者：

Gamage, Nipuni-Dhanesha H. ^{[1
]}

Mei, Yujiang ^{[1
]}

Garcia, Joel ^{[1
]}

Allen, Matthew J. ^{[1
]}

机构：

[1] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 47期

基金：

美国国家卫生研究院;

关键词：

chelates; cryptands; europium; lanthanides; redox chemistry; EU-II COMPLEXES; ALKALINE-EARTH; WATER EXCHANGE; YTTERBIUM; LUMINESCENCE; KINETICS;

D O I：

10.1002/anie.201002789

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of cryptands has been prepared and they demonstrate the relationship between oxidative stability of aqueous EuII and ligand properties (see figure). One of these EuII complexes is more stable than FeII in hemoglobin and appears to be the most oxidatively-stable aqueous EuII species known. The high stability of EuII is expected to enable the use of the unique magnetic and optical properties of this ion in vivo. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8923 / 8925

页数：3

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