Hydrogenation of carbon dioxide on copper in a H+ conducting membrane-reactor

被引：31

作者：

Karagiannakis, G

Zisekas, S

Stoukides, M

机构：

[1] Dept Chem Engn, Salonika 54124, Greece

[2] Chem Proc Engn Res Inst, Salonika 54124, Greece

来源：

SOLID STATE IONICS | 2003年 / 162卷

关键词：

solid state proton conductor; copper electrode; electrocatalytic hydrogenation of carbon dioxide; reverse water gas shift reaction;

D O I：

10.1016/S0167-2738(03)00227-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The CO2-H-2 reaction was studied at 823-1023 K in a double-chamber proton conducting cell-reactor. The proton conductor was a strontia-zirconia-yttria (SZY) perovskite of the form: SrZr0.90Y0.10O3-alpha The working (cathodic) electrode was a polycrystalline copper film. In the catalytic mode of operation, the reactants were gaseous mixtures of CO2 and H-2 diluted in He and in the electrocatalytic mode, mixtures Of CO2 and He were introduced over the cathode while hydrogen was supplied as H.. The catalytic activity and selectivity of H+ is compared to that of gaseous H-2. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：313 / 318

页数：6