Solvent-free fabrication of proton-conducting membranes based on commercial elastomers

被引：9

作者：

He, Shaojian ^{[1
]}

Lin, Yankai ^{[1
]}

Wei, Zheng ^{[2
]}

Zhang, Liqun ^{[2
]}

Lin, Jun ^{[1
]}

Nazarenko, Seigei ^{[3
]}

机构：

[1] North China Elect Power Univ, Sch Renewable Energy, Beijing 102206, Peoples R China

[2] Beijing Univ Chem Technol, Key Lab Nanomat, Minist Educ, Beijing, Peoples R China

[3] Univ So Mississippi, Sch Polymers & High Performance Mat, Hattiesburg, MS 39406 USA

来源：

POLYMERS FOR ADVANCED TECHNOLOGIES | 2015年 / 26卷 / 04期

基金：

中国国家自然科学基金;

关键词：

proton exchange membrane; elastomer; solvent-free; in situ reaction; METHANOL FUEL-CELLS; POLYSTYRENE-BUTADIENE RUBBER; CHLOROSULFONIC ACID; EXCHANGE MEMBRANES; SYSTEMS; SULFONATION; POLYMERS; BLENDS; NAFION; SPEEK;

D O I：

10.1002/pat.3443

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Five different types of elastomers were examined as the matrix materials in the preparation of non-fluorinated proton exchange membranes utilizing a solvent-free route via the in situ reaction of sodium 4-styrenesulfonate (NaSS). The morphology of the elastomer/NaSS vulcanizates was studied to evaluate the effect of polarity, viscosity and saturation degree of the elastomer matrixes. Much better dispersion of NaSS was found in chlorosulfonated polyethylene rubber (CSM) and hydrogenated nitrile butadiene rubber (HNBR) matrixes than in the other three types of elastomer matrixes. For CSM/NaSS and HNBR/NaSS proton exchange membranes, distinctive membrane properties were observed and correlated with their different structure and morphologies. The CSM/NaSS membranes exhibited the proton conductivity as high as similar to 0.03Scm(-1) and the selectivity (the ratio of proton conductivity to methanol permeability) higher than that of Nafion. Copyright (c) 2015 John Wiley & Sons, Ltd.

引用

页码：300 / 307

页数：8

共 21 条

[1] Polymeric proton conducting systems based on commercial elastomers.: III.: Microstructural and electrical characterization of films based on HSBS/EPDM/PP/PS/silica [J].

Escribano, P. G. ;

Nacher, A. ;

Del Rio, C. ;

Gonzalez, L. ;

Acosta, J. L. .

JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 102 (01) :13-21

[2] Preparation and Characterization of Hybrid Membranes for Fuel Cell Applications: EPDM Filled with Organophilized Silicas [J].

Escribano, P. G. ;

Canovas, M. J. ;

Ojeda, M. C. ;

Del Rio, C. ;

Sanchez, F. ;

Acosta, J. L. .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2009, 47 (12) :1203-1210

[3] Preparation, characterization and single cell testing of new ionic conducting polymers for fuel cell applications [J].

Escribano, P. G. ;

del Rio, C. ;

Acosta, J. L. .

JOURNAL OF POWER SOURCES, 2009, 187 (01) :98-102

[4] Polymeric proton conducting systems based on commercial elastomers.: II.: Synthesis and microstructural characterization of films based on HSBR/EPDM/PP/PS/Silica [J].

Escribano, PG ;

Nacher, A ;

Del Rio, C ;

González, L ;

Acosta, JL .

JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 93 (05) :2394-2402

[5] Preparation and characterization of high performance sulfonated poly(p-phenylene-co-aryl ether ketone) membranes for direct methanol fuel cells [J].

He, Qingyi ;

Zheng, Jifu ;

Zhang, Suobo .

JOURNAL OF POWER SOURCES, 2014, 260 :317-325

[6] Thermodynamic Study of the Sulphonation of Polystyrene-Butadiene Rubber with Chlorosulphonic Acid for Proton Exchange Membrane Fuel Cell [J].

Idibie, C. A. ;

Abdulkareem, A. S. ;

Pienaar, H. C. vZ. ;

Iyuke, S. E. ;

vanDyk, L. .

JOURNAL OF APPLIED POLYMER SCIENCE, 2010, 117 (03) :1766-1771

[7] Synthesis of Low Methanol Permeation Polymer Electrolyte Membrane from Polystyrene-Butadiene Rubber [J].

Idibie, C. A. ;

Abdulkareem, A. S. ;

Pienaar, H. C. vZ. ;

Iyuke, S. E. ;

Van Dyk, L. .

POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2009, 48 (11) :1121-1129

[8] Mechanism and Kinetics of Sulfonation of Polystyrene-Butadiene Rubber with Chlorosulfonic Acid [J].

Idibie, Christopher A. ;

Abdulkareem, Saka A. ;

Pienaar, Christo H. vZ ;

Iyuke, Sunny E. ;

vanDyk, Lizelle .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (04) :1600-1604

[9] Polymeric materials for fuel cells: concise review of recent studies [J].

Jagur-Grodzinski, Joseph .

POLYMERS FOR ADVANCED TECHNOLOGIES, 2007, 18 (10) :785-799

[10] Stretched recast Nafion for direct methanol fuel cells [J].

Lin, J. ;

Wycisk, R. ;

Pintauro, P. N. ;

Kellner, M. .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2007, 10 (01) :B19-B22

← 1 2 3 →