Ultrafine TiO2 powders prepared from aqueous TiCl4 solutions at room temperature

被引:0
作者
Hongliang Yi [1 ,2 ]
Jie Zhang [2 ]
Mingtu Ma [1 ]
Hao Zhang [3 ]
Bongho Lee [4 ]
Jeungsoo Huh [4 ]
机构
[1] Chongqing Inst Automobile Res, Dept Mat Sci & Technol, Chongqing 400039, Peoples R China
[2] Harbin Inst Technol, Dept Mat Sci, Harbin 150001, Peoples R China
[3] China Chongqing Automobile Res Inst, Chongqing Key Lab Vehicle Emiss & Economiz Energy, Chongqing 400039, Peoples R China
[4] Kyungpook Natl Univ, Dept Mat Sci & Met, Taegu 702701, South Korea
来源
PROGRESSES IN FRACTURE AND STRENGTH OF MATERIALS AND STRUCTURES, 1-4 | 2007年 / 353-358卷
关键词
Titania; precipitating; nano; room temperature;
D O I
10.4028/www.scientific.net/KEM.353-358.2135
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Ultrafine TiO2 powders as rutile and anatase phase were simply precipitated at room temperature for only tens of hours by simply controlling the pH value and Ti4+ concentration via aqueous TiCl4 solution. Under the optimal pH value and Ti4+ concentration, the average particle size of powders with rutile phase was 3.7nm, while that of powders with anatase phase was 3.0nm. The average particle size was calculated from the broadening of corresponding X-ray spectral peaks by Scherrer formula. In addition, 3.0 mol.1(-1) are suggested to be used as concentration of stock solutions instead of the current concentration 2.0 mol.1(-1).
引用
收藏
页码:2135 / +
页数:2
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