Ultrafast excited-state dynamics in biological environments

被引:5
作者
Fuerstenberg, Alexandre [1 ]
Vauthey, Eric [1 ]
机构
[1] Univ Geneva, Dept Phys Chem, CH-1211 Geneva 4, Switzerland
关键词
excited-state quenching; fluorescence polarization anisotropy; fluorescent probes; solvation dynamics; vibrational energy relaxation;
D O I
10.2533/chimia.2007.617
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We discuss and illustrate by several examples how the ultrafast excited-state dynamics of a chromophore can be altered when changing its environment from a homogenous solution to a biological molecule such as proteins or nucleic acids.
引用
收藏
页码:617 / 620
页数:4
相关论文
共 25 条
  • [1] Elementary steps in excited-state proton transfer
    Agmon, N
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (01) : 13 - 35
  • [2] Power-law solvation dynamics in DNA over six decades in time
    Andreatta, D
    Lustres, JLP
    Kovalenko, SA
    Ernsting, NP
    Murphy, CJ
    Coleman, RS
    Berg, MA
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (20) : 7270 - 7271
  • [3] Connecting chemical dynamics in gases and liquids
    Elles, Christopher G.
    Crim, F. Fleming
    [J]. ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 2006, 57 : 273 - 302
  • [4] Ultrafast excited-state dynamics of DNA fluorescent intercalators:: New insight into the fluorescence enhancement mechanism
    Fuerstenberg, Alexandre
    Julliard, Marc D.
    Deligeorgiev, Todor G.
    Gadjev, Nikolai I.
    Vasilev, Aleksey A.
    Vauthey, Eric
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (23) : 7661 - 7669
  • [5] FURSTENBERG A, 2007, IN PRESS CHEM EUR J
  • [6] FURSTENBERG A, 2006, FEMTOCHEMISTRY, V7
  • [7] FURSTENBERG A, 2007, IN PRESS J PHYS CHEM
  • [8] FURSTENBERG A, 2005, PHOTOCHEM PHOTOBIOL, P260
  • [9] Chemical dynamics in proteins: The photoisomerization of retinal in bacteriorhodopsin
    Gai, F
    Hasson, KC
    McDonald, JC
    Anfinrud, PA
    [J]. SCIENCE, 1998, 279 (5358) : 1886 - 1891
  • [10] Probing polar solvation dynamics in proteins: A molecular dynamics simulation analysis
    Golosov, Andrei A.
    Karplus, Martin
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (06) : 1482 - 1490