Fixation of atmospheric carbon dioxide by ruthenium complexes bearing an NHC-based pincer ligand: formation of a methylcarbonato complex and its methylation

被引：24

作者：

Arikawa, Yasuhiro ^{[1
]}

Nakamura, Takuo ^{[1
]}

Ogushi, Shinji ^{[1
]}

Eguchi, Kazushige ^{[1
]}

Umakoshi, Keisuke ^{[1
]}

机构：

[1] Nagasaki Univ, Grad Sch Engn, Div Chem & Mat Sci, Nagasaki 8528521, Japan

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 12期

关键词：

ZINC(II) TETRAAZACYCLOALKANE COMPLEXES; FACILE CO2 UPTAKE; REDUCTIVE ELIMINATION; REACTION-MECHANISM; STRUCTURAL-CHARACTERIZATION; DIRECT CARBOXYLATION; INSERTION REACTIONS; ALKOXIDE COMPLEXES; ORGANIC CARBONATES; DIMETHYL CARBONATE;

D O I：

10.1039/c5dt00476d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A methylcarbonato ruthenium complex was prepared by capture of CO2 from air using the (CNC)(bpy)Ru scaffold. The methylcarbonato complex was relatively inert to decarboxylation. Treatments with methylating reagents released dimethylcarbonate.

引用

页码：5303 / 5305

页数：3

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