Synthesis and characterization of anionic and cationic poly(ferrocenylsilane) polyelectrolytes

被引：61

作者：

Hempenius, MA ^{[1
]}

Brito, FF ^{[1
]}

Vancso, GJ ^{[1
]}

机构：

[1] Twente Univ Technol, Res Inst Nanotechnol, MESA, NL-7500 AE Enschede, Netherlands

来源：

MACROMOLECULES | 2003年 / 36卷 / 17期

关键词：

D O I：

10.1021/ma034432g

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(ferrocenylsilane) polyanions and polycations were synthesized by treating poly(ferrocenyl(3-halopropyl)-methylsilanes) with a variety of nucleophiles, ranging from alkali metal amides and neutral amines to ester enolate anions. Highly water-soluble weak and strong organometallic polyelectrolytes were obtained. Analysis of the polyelectrolytes by GPC demonstrated that the organometallic polymers did not undergo chain scission under the employed reaction conditions.

引用

页码：6683 / 6688

页数：6

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