NMR determination of site-specific deuterium distribution (SNIF-NMR) in squalene from different sources

被引：0
|
作者：
Deiana, M
Corongiu, FP
Dessi, MA
Scano, P
Casu, M
Lai, A
机构：
[1] Univ Cagliari, Dipartimento Sci Chim, I-09042 Cagliari, Italy
[2] Univ Cagliari, Dipartimento Biol Sperimentale, Sez Patol Sperimentale, I-09042 Cagliari, Italy
来源：
MAGNETIC RESONANCE IN CHEMISTRY | 2001年 / 39卷 / 01期
关键词：
NMR; H-2; deuterium; squalene; liver oil; olive oil; food analysis; SNIF-NMR;
D O I：
10.1002/1097-458X(200101)39:1<29::AID-MRC796>3.0.CO;2-#
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The H-2 NMR spectra of squalene from shark liver oil and olive oil sources were investigated by the SNIF-NMR technique. The areas of the absorption signals of the olefinic, methylene and methyl sites were carefully determined, and the deuterium distribution among the various sites was shown to depart from the statistical distribution in a way that is different for squalene from different sources. The results are discussed in connection with the different biosynthetic pathways of squalene involved in plants and animals. Copyright (C) 2001 John Wiley & Sons, Ltd.
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页码：29 / 32
页数：4
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