Reason for different solubility of alkali metal chlorides in cadmium nitrate solution

被引：0

作者：

Khripun, MK ^{[1
]}

Kiselev, AA ^{[1
]}

机构：

[1] St Petersburg State Univ, St Petersburg, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2003年 / 73卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

Chloride; Nitrate; Hydrate; Cadmium; Alkali Metal;

D O I：

10.1023/A:1024704531823

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An idea that concentrated solutions of salts forming several crystal hydrates can be considered as systems of mixed solvents was developed within the framework of a phenomenological model of solution structure for the systems Cd(NO3)(2)-MCl-H2O (M = Li, Na, K, Cs). It was supposed that LiCl and CsCl preferentially interact with a solvent like Cd(NO3)(2) nanohydrate, whereas NaCl and KCl, with a solvent like Cd(NO3)(2) tetrahydrate.

引用

页码：161 / 164

页数：4