An efficient and recoverable palladium organocatalyst for Suzuki reaction in aqueous media

被引：11

作者：

Fareghi-Alamdari, Reza ^{[1
]}

Golestanzadeh, Mohsen ^{[1
,2
]}

Bagheri, Omid ^{[3
]}

机构：

[1] Malek Ashtar Univ Technol, Coll Chem & Chem Engn, Tehran 167653454, Iran

[2] Univ Kashan, Dept Organ Chem, Fac Chem, Kashan 8731751167, Iran

[3] Univ Kashan, Dept Inorgan Chem, Fac Chem, Kashan 8731751167, Iran

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2017年 / 31卷 / 09期

关键词：

cross-coupling reaction; heterogeneous catalyst; organocatalyst; reusable; water media; CROSS-COUPLING REACTIONS; ORGANOBORON COMPOUNDS; MIYAURA REACTION; CARBOCYCLIC CARBENE; ROOM-TEMPERATURE; ARYL CHLORIDES; WATER; COMPLEXES; CATALYSTS; LIGANDS;

D O I：

10.1002/aoc.3698

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Meso-tetrakis[4-(methoxycarbonyl)phenyl]porphyrinatopalladium(II) as a palladium organocatalyst was synthesized and then used in aqueous media as a heterogeneous organocatalyst in Suzuki reaction. The prepared organocatalyst was characterized using UV-visible, infrared and NMR spectroscopies. It was found to be an efficient catalyst for Suzuki coupling reaction between phenylboronic acid and a broad range of aryl halides. Mild reaction conditions, water solvent as green media, and easy catalyst separation and reusability are the advantages of the presented method.

引用

页数：8

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