Spatially resolved NMR thermometry of an operating fixed-bed catalytic reactor

被引：39
作者：
Koptyug, Igor V. [1 ]
Khomichev, Alexey V. [1 ]
Lysova, Anna A. [1 ]
Sagdeev, Renad Z. [1 ]
机构：
[1] SB RAS, Int Tomog Ctr, Novosibirsk, Russia
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 32期
关键词：
D O I：
10.1021/ja802075m
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An MRI-based approach for the thermometry of an operating packed-bed catalytic reactor was implemented. It was employed for the spatially resolved NMR thermometry of the bed of Pd/y-Al(2)O(3) catalyst beads in the course of propylene hydrogenation reaction. This was achieved by detecting the spatially resolved axial 1D profiles of the (27)Al NMR signal intensity of Al(2)O(3) in the course of the reaction. The experimental results demonstrate a clear correlation between the (27)Al NMR signal intensity and the catalyst temperature measured with a thermocouple (25-250 degrees C), and reveal the existence of pronounced temperature gradients along the catalyst bed.
引用
收藏
页码：10452 / +
页数：3
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[21]   EXPERIMENTAL EVALUATION OF DYNAMIC MODELS FOR A FIXED-BED CATALYTIC REACTOR [J].
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FOSS, AS .
ADVANCES IN CHEMISTRY SERIES, 1972, (109) :48-&
[22]   Forced oscillations in concentration in a tubular, fixed-bed, catalytic reactor [J].
Thullie, J. ;
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Rinker, R.G. .
International chemical engineering, 1988, 28 (04) :723-730
[23]   PULSATION IN A FIXED-BED REACTOR [J].
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SMITH, JM .
AICHE JOURNAL, 1963, 9 (05) :677-680
[24]   SIMULATION AND OPTIMIZATION OF A FIXED-BED REACTOR OPERATING IN COKING REGENERATION CYCLES [J].
BORIO, DO ;
MENENDEZ, M ;
SANTAMARIA, J .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1992, 31 (12) :2699-2707
[25]   CATALYTIC-OXIDATION OF CYCLOHEXANE IN FIXED-BED REACTOR - COMPARISON WITH RESULTS IN FLUIDIZED-BED REACTOR [J].
COSTALOPEZ, J ;
RIVERARECIO, P .
ANALES DE QUIMICA, 1977, 73 (03) :445-453
[26]   Saucy-Marbet ketonization in a continuous fixed-bed catalytic reactor [J].
Frauchiger, S ;
Baiker, A .
APPLIED CATALYSIS A-GENERAL, 2003, 253 (01) :33-48
[27]   Approximate characteristics of a moving temperature front in a fixed-bed catalytic reactor [J].
Burghardt, A ;
Berezowski, M ;
Jacobsen, EW .
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[29]   FIXED-BED CATALYTIC REACTOR SIMULATION FOR EXOTHERMIC COMPLEX REACTION. [J].
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