Photochemistry of bicyclo[2.2.2]octenones: an uncommon oxidative decarbonylation

被引：20

作者：

Lee, TH ^{[1
]}

Rao, PD ^{[1
]}

Liao, CC ^{[1
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30043, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 09期

关键词：

D O I：

10.1039/a901182j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Several substituted 3,3-dialkoxy-5-methoxycarbonyIbicyclo[2.2.2]oct-5-en-2-ones underwent unusual oxidative decarbonylation to produce polysubstituted cyclohexenes upon direct irradiation and usual ODPM rearrangement under sensitized conditions. A plausible mechanism for the oxidative decarbonylation is also given.

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页码：801 / 802

页数：2

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