A New Solvent-Free Reaction for the Preparation of Alkoxysilane from Cyclic Ethers, Alcohols, or Carbonyl Compounds

被引：22

作者：

Pehlivan, Leyla ^{[1
]}

Metay, Estelle ^{[1
]}

Boyron, Olivier ^{[2
]}

Demonchaux, Patrice ^{[3
]}

Mignani, Gerard

Lemaire, Marc ^{[1
]}

机构：

[1] Univ Lyon 1, Lab Catalyse & Synth Organ, ICBMS, CNRS,UMR 5246, F-69622 Villeurbanne, France

[2] CNRS, UMR 5265, Lab Chim Catalyse Polymeres & Procedes C2P2, F-69616 Villeurbanne, France

[3] Minakem SAS, F-59310 Beuvry La Foret, France

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 2011卷 / 24期

关键词：

Reduction; Protecting groups; Palladium; Ethers; Heterogeneous catalysis; Silanes; CATALYZED REDUCTION; SELECTIVE REDUCTION; ORGANIC-COMPOUNDS; NITRO-COMPOUNDS; REDUCING AGENT; PALLADIUM; EPOXIDES; CLEAVAGE; HYDROGEN; HYDRIDE;

D O I：

10.1002/ejoc.201100489

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 1,1,3,3-tetramethyldisiloxane/Pd/C system is reported here as a new method to accomplish the ring-opening of ethers and epoxides to give protected alcohols. The approach can also be used for the protection of primary or secondary alcohols and for the reduction of aldehydes and ketones to obtain alkoxysilanes.

引用

页码：4687 / 4692

页数：6

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