Diversification of copper complexes with 2,2′-bipyridyl ligand bearing benzylthio groups due to the different gas atmosphere

被引：1

作者：

Wang, Peng-min ^{[1
]}

Liang, Rui ^{[1
]}

Chen, Yuan ^{[1
]}

Liu, Ao-gang ^{[1
]}

Ma, Zhao ^{[1
]}

Li, Bao ^{[1
]}

Zhang, Tianle ^{[1
]}

机构：

[1] Huazhong Univ Sci & Technol, Semicond Chem Ctr, Sch Chem & Chem Engn, Key Lab Mat Chem Energy Convers & Storage,Hubei Ke, Wuhan 430074, Hubei, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2022年 / 543卷

关键词：

Copper cluster; Crystal structure; 22'-bipyridyl ligand; ELECTROCHEMICAL REDUCTION; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; BIPYRIDYL; PHOTOLUMINESCENCE; REACTIVITY; CHEMISTRY; CLUSTER; ACID; CU;

D O I：

10.1016/j.ica.2022.121151

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of CuI with 5,5 '-bis((benzylthio)methyl)-2,2 '-bipyridine could produce two complexes under different gas atmosphere. Via SCXRD characterizations, the mixed-valence Cu-II/Cu(I )complex could be obtained under ambient atmosphere, while Cu-II complex with oxalate could be produced via the reduction of CO2.

引用

页数：5

共 39 条

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