Pd(0)-Schiff-base@MCM-41 as high-efficient and reusable catalyst for C-C coupling reactions

被引:53
作者
Nikoorazm, Mohsen [1 ]
Ghorbani-Choghamarani, Arash [1 ]
Panahi, Atefeh [1 ]
Tahmasbi, Bahman [1 ]
Noori, Nourolah [1 ]
机构
[1] Ilam Univ, Dept Chem, Fac Sci, POB 69315516, Ilam, Iran
关键词
Mesoporous; MCM-41; Palladium; Heck reaction; Suzuki reaction; C-C coupling; PALLADIUM COMPLEX; FUNCTIONALIZED MCM-41; SUZUKI; HECK; NANOPARTICLES; NANOCATALYST; SILICA; ACID;
D O I
10.1007/s13738-017-1222-x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A Pd-Schiff-base grafted on functionalized mesoporous MCM-41 (Pd(0)-Schiff-base@MCM-41) was prepared using a post-grafting procedure and used as a highly efficient and reusable nanostructural catalyst for the carbon-carbon cross-coupling reactions of various aryl halides (including aryl iodide, bromide and chloride) with sodium tetraphenyl borate, phenylboronic acid and butyl acrylate. This catalyst exhibits interesting reactivity through Heck and Suzuki reactions.
引用
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页码:181 / 189
页数:9
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